All Questions
Tagged with acid-base inorganic-chemistry
438
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Why is phosphoric acid a weak acid?
What is the reason for the phosphoric acid $\ce{H3PO4}$ being a weak acid despite having a structure similar to that of sulfuric acid $\ce{H2SO4}?$
I found some sources claiming that the resonance of ...
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Phase diagram of ammonium hydrosulfide, a volatile salt
Salts (ionic compounds) usually have low volatility due to the strong ionic bond.
However, there are exceptions. Smelling salts decompose and release ammonia gas.
What is "volatile"?
If a ...
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1
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Amphoteric character of V2O5
In my NCERT textbook, in the chapter 'The d- and f-block elements', the last paragraph under oxides and oxoanions of metals goes like this:
$(...)$ $\ce{V2O5}$ is, however, amphoteric though mainly ...
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2
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Reaction between copper rod and carbon rod in hydrochloric acid [closed]
The situation is this: a copper rod and a carbon rod, touching each other, are submerged in HCl(aq). We're asked to describe the reaction that occurs, but as far as I can see, there's no reaction? The ...
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1
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Can phosphorous penta hydroxide [P(OH)5] exist? [closed]
I was looking at the oxyacids of Phosphorous and it is given that (in Wikipedia article of "Phosphorous acid"), some of these acids (Eg: $H_3PO_2$ and $H_3PO_3$) exist in a dynamic ...
4
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Acidity of H4P2O7 and H3PO4
As given in pKa of H4P2O7 and H3PO4. The acidity of pyrophosphoric acid is clearly stronger than phosphoric acid. The two acid structures is given below.
Thought: Consider the pyrophosphoric acid ...
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2
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Stability of H3MnO4, H2MnO4, HMnO4
I cannot seek out the reason why while $\ce{H3PO4}$ (phosphorus oxidation +5) is relatively stable and obtainable but $\ce{H3MnO4}$ (the same oxidation state +5) is rarely mentioned and perhaps ...
2
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Calculating the pH after adding hydrochloric acid to the potassium hydrogen phosphate solution
I am trying to calculate the $\mathrm{pH}$ of a solution obtained by mixing $\pu{20.00 mL}$ of $\pu{0.2 M}$ potassium hydrogen phosphate solution and $\pu{10.00 mL}$ of $\pu{0.25 M}$ hydrochloric acid ...
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Why is it that in a buffer solution the equilibrium concentrations may be assumed to be the initial concentrations? [duplicate]
Considering the Henderson–Hasselbalch equation,
$$\text{pH} = \text{p}K_a + \lg \frac{[\ce{AcO⁻}]} {[\ce{AcOH}]}$$
$$\text{p}K_a = \lg \frac{[\ce{AcO⁻}][\ce{H⁺}]} {[\ce{AcOH}]}$$
Why are the values ...
7
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Do peroxy acids such as peroxynitric acid have anhydrides?
Anhydrides reversibly react with water to form a respective acid or base. For example, $\ce{CO2}$ is the anhydride of $\ce{H2CO3}$:
$$\ce{CO2 + H2O <=> H2CO3}.\tag{R1}$$
Acidic anhydride can be ...
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2
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How to neutralize 60L of a 2% Aqua Regia with Various Metals suspended
I am encountering an issue in my laboratory. My supervisor and I are currently faced with the task of neutralizing a volume of 60 liters of Aqua Regia, which contains suspended metals, at a ...
13
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3
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Why Is Hydrogen in HSO3- Connected to Oxygen Instead of Sulfur?
One of the questions in my homework was to draw $\ce{HSO3-}$, which I thought to be pretty easy. Sulfur is the least electronegative (except hydrogen but it can't be the central atom), hence it is the ...
1
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1
answer
107
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What are the dissociation constants of hydronium and hydroxide ions? [duplicate]
Context
The answer to How to calculate Ka for hydronium and Kb for hydroxide?, water was regarded as solvent once and base (or equivalently acid) once while citing Reference 1 (1986) and made no ...
7
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1
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338
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Why is fluoroantimonic acid so unique?
Fluoroantimonic acid is the strongest acid because its conjugate base $\ce{SbF6-}$ is exceptionally stable. $\ce{SbF6-}$ is in perfect octahedral symmetry wherein the negative charge is equally shared ...
6
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Why does phosphinic acid not form pyroacids?
Why does $\ce{H3PO2}$ not form pyroacids? All I know is pyroacids are derived oxyacids obtained by removing one $\ce{H2O}$ molecule from two molecules of oxyacids. Correct me if this is wrong.