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1 vote
2 answers
245 views

Stability of H3MnO4, H2MnO4, HMnO4

I cannot seek out the reason why while $\ce{H3PO4}$ (phosphorus oxidation +5) is relatively stable and obtainable but $\ce{H3MnO4}$ (the same oxidation state +5) is rarely mentioned and perhaps ...
Shira's user avatar
  • 610
5 votes
1 answer
491 views

Why is water present in "pure" nitric acid and RFNA and WFNA?

Various types of nitric acid have been used in rocket fuels as oxidisers (RFNA is red fuming nitric acid, WFNA is white fuming nitric acid) as they are often hypergolic with a wide variety of fuels. ...
matt_black's user avatar
2 votes
1 answer
226 views

Why and how do aqueous silica systems precipitate and can its occurrence be mitigated by quantifying its speciation correctly?

Background/Context: For context, I have been doing a lot of work on experimental systems in geopolymer chemistry lately with a focus on "activator" solutions which are essentially mixtures ...
Hendrix13's user avatar
  • 500
3 votes
0 answers
156 views

What is the relation between strength of a base and the thermal stability of its salts?

In Concise Inorganic Chemistry, $5^{th}$ edition, by JD Lee, while discussing oxides and hydroxides of Group $2$ metals, it has been stated that: The increase in basic strength is illustrated by the ...
Ritam_Dasgupta's user avatar
0 votes
0 answers
65 views

Adding a base and a salt to a hydrated complex

The question goes like this: $\ce{Fe(NO3)3}$ V= $\pu{1 liter}$ and $\ce{[Fe(NO3)3]} =\pu{0.1 moles/liter}$. Calculate the $\mathrm{pH}$ of this solution using the values of $K$ given. We add a solid ...
Olivier Vandenryt's user avatar
8 votes
3 answers
487 views

Is trisulfuric acid hypothetical?

In the preparation of sulfuric acid through contact process, Hot sulfur trioxide passes through the heat exchanger and is dissolved in concentrated $\ce{H2SO4}$ in the absorption tower to form oleum: ...
Nilay Ghosh's user avatar
  • 26.3k
3 votes
0 answers
290 views

If both nitric acid and nitrate ion are stabilised through resonance, what makes the nitrate ion more stable in aqueous medium?

If both nitric acid and nitrate ion are stabilised through resonance, what makes the nitrate ion more stable in aqueous medium? Can the same argument be applied to nitrous acid and nitrite ion in ...
Jack Bing's user avatar