All Questions
7
questions
1
vote
2
answers
245
views
Stability of H3MnO4, H2MnO4, HMnO4
I cannot seek out the reason why while $\ce{H3PO4}$ (phosphorus oxidation +5) is relatively stable and obtainable but $\ce{H3MnO4}$ (the same oxidation state +5) is rarely mentioned and perhaps ...
5
votes
1
answer
491
views
Why is water present in "pure" nitric acid and RFNA and WFNA?
Various types of nitric acid have been used in rocket fuels as oxidisers (RFNA is red fuming nitric acid, WFNA is white fuming nitric acid) as they are often hypergolic with a wide variety of fuels.
...
2
votes
1
answer
226
views
Why and how do aqueous silica systems precipitate and can its occurrence be mitigated by quantifying its speciation correctly?
Background/Context:
For context, I have been doing a lot of work on experimental systems in geopolymer chemistry lately with a focus on "activator" solutions which are essentially mixtures ...
3
votes
0
answers
156
views
What is the relation between strength of a base and the thermal stability of its salts?
In Concise Inorganic Chemistry, $5^{th}$ edition, by JD Lee, while discussing oxides and hydroxides of Group $2$ metals, it has been stated that:
The increase in basic strength is illustrated by the ...
0
votes
0
answers
65
views
Adding a base and a salt to a hydrated complex
The question goes like this:
$\ce{Fe(NO3)3}$ V= $\pu{1 liter}$ and $\ce{[Fe(NO3)3]} =\pu{0.1 moles/liter}$.
Calculate the $\mathrm{pH}$ of this solution using the values of $K$ given.
We add a solid ...
8
votes
3
answers
487
views
Is trisulfuric acid hypothetical?
In the preparation of sulfuric acid through contact process,
Hot sulfur trioxide passes through the heat exchanger and is dissolved in concentrated $\ce{H2SO4}$ in the absorption tower to form oleum:
...
3
votes
0
answers
290
views
If both nitric acid and nitrate ion are stabilised through resonance, what makes the nitrate ion more stable in aqueous medium?
If both nitric acid and nitrate ion are stabilised through resonance, what makes the nitrate ion more stable in aqueous medium?
Can the same argument be applied to nitrous acid and nitrite ion in ...