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Questions tagged [hamiltonian]

The central term in the hamiltonian formalism. Can be interpreted as an energy input, or "true" energy.

1 vote
2 answers
98 views

Is many-electron system's energy bounded from above?

A many-electron system with molecular Hamiltonian under the Born-Oppenheimer approximation has a finite ground state energy, which means its eigenenergy is bounded from below. In my research, I need ...
Andy Liu's user avatar
1 vote
0 answers
52 views

Perturbation theory: Why is the inner product expressed as $\langle\psi_m^0|H'|\psi_n^0\rangle=-2V_0(-1)^{\frac{m+1}{2}}$? [closed]

Introducing a perturbation to an unperturbed state, say $\psi_n^0$, with eigenenergy $E_n^0$ yields the first degenerate state as: $$\psi_n^1=\sum_{m\neq n}\frac{\langle\psi_m^0|H'|\psi_n^0\rangle}{(...
Rasmus Andersen's user avatar
1 vote
0 answers
57 views

Determining the Hermitian operator in a Foldy-Wouthuysen transformation

I am following the mathematical steps of a paper and at some point the authors consider a transformed Hamiltonian of the form $$ \mathcal{H}' = e^{iS} \mathcal{H} e^{-iS}. $$ They then follow a ...
Ron Stean's user avatar
4 votes
1 answer
126 views

Non-symplectic Hamiltonian systems

I'm wondering when the phase space of a Hamiltonian system looses its symplectic structure. I think it happens when the Hamiltonian $H$ depends on a set of other variables $S_1,...,S_k$ as well as on ...
Gyro's user avatar
  • 143
5 votes
1 answer
244 views

Details in the derivation of the Lippmann-Schwinger equation

So the argument goes that for a slightly perturbed Hamiltonian $$ H = H_0 + V, $$ there will be some exactly known states, $\left|\phi\right>$, solving $$ H_0\left|\phi\right> = E\left|\phi\...
Depenau's user avatar
  • 525
0 votes
0 answers
54 views

Expectation values of fermionic operators

I'm trying to compute the matrix elements of an Hamiltonian expressed in terms of fermionic operators. The system is an Agassi model, N interacting fermions on 2 levels separated by energy $\epsilon$, ...
Delan's user avatar
  • 1
2 votes
0 answers
60 views

Question on derivation of Schrödinger's equation [closed]

I have recently started reading Nanoscale Physics for Materials Science by Tsurumi et al. and the authors present a unique derivation of Schrödinger's equation in the first chapter: I was wondering ...
hieronymus_derz's user avatar
0 votes
0 answers
27 views

Energy Operator, Hamiltonian, Energy Eigenvalues [duplicate]

Can we use the energy operator $i\hbar\frac{\partial}{\partial t}$ instead of the Hamiltonian to obtain the energy eigenvalues?
robın3162's user avatar
1 vote
2 answers
102 views

Equations of motion and infinitesimal canonical transformations

Currently, I'm diving into infinitesimal canonical transformations, with a particular focus on using the infinitesimal change $\epsilon=\delta t$ and $H$ as our generating function. So, in this ...
user353399's user avatar

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