All Questions
Tagged with equilibrium solutions
59
questions
-1
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1
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74
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Considering Le Chatelier's principle, what happens when you add more solute to a saturated solution already in equilibrium?
If I'm not wrong saturated solutions are in dynamic equilibrium. Will the addition of solute disturb the equilibrium? What exactly occurs and how to apply Le Chatelier's principle?
-5
votes
1
answer
106
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Find the pH of a solution obtained by mixing 100 ml 0.1m Na3PO4 and 100 ml 0.1 M NaH2PO4. Given that H3PO4: [Κα₁ = 10^-4, Κα₂ = 10^-7, Каз = 10^-11] [closed]
So, my query is that since NaH2PO4 is a weak acid, and Na3PO4 is a basic salt, wouldn't they react? Another theory was that since NaH2PO4 is a weak acid and Na3PO4 is a salt of strong acid and NaH2PO4,...
2
votes
4
answers
168
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How can the Kw of water be constant?
I know in neutral solution, $\ce{[H+]}= \ce{[OH-]}= \pu{1.0 x 10^-7}$.
However, let’s say I add an acid like HCl. This will increase $\ce{[H+]}$, therefore it’s no longer $\pu{1.0 x 10^-7}$, but is ...
1
vote
0
answers
41
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Why is it that in a buffer solution the equilibrium concentrations may be assumed to be the initial concentrations? [duplicate]
Considering the Henderson–Hasselbalch equation,
$$\text{pH} = \text{p}K_a + \lg \frac{[\ce{AcO⁻}]} {[\ce{AcOH}]}$$
$$\text{p}K_a = \lg \frac{[\ce{AcO⁻}][\ce{H⁺}]} {[\ce{AcOH}]}$$
Why are the values ...
3
votes
2
answers
2k
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Calculate the titer of a solution
I hope this is the right place to ask. We have this exercise without solution
One litre of diluted sodium hydroxide solution (c = 0.15mol/litre) is
to be prepared in the laboratory. The titer from ...
1
vote
0
answers
69
views
Would a container made of sugar eventually dissolve if filled with a sugar-saturated solution of water?
Suppose you had a bottle made of sugar glass, and filled it with water that was already saturated with sugar.
I know that with a fully saturated solution of sugar in water, no additional sugar can ...
1
vote
3
answers
985
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Why does equilibrium of ice and water only exist at 273K at normal pressure?
I am a high school student and I am a little confused in the concept of spontaneity of a reaction and how equilibrium works for a reaction, I got some confusions:
Let's take example of freezing of ...
1
vote
1
answer
108
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Why does Raoult's Law have a weighted sum instead of a direct sum?
I'm fully aware of the various questions asked about Raoult's Law, and I'm asking this after having gone through all of them and not finding a suitable answer to my question.
I have studied, that at a ...
4
votes
1
answer
158
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Why is the van ’t Hoff relation an approximation?
Lately, I've been looking and thinking about the fact that a professor told us in an advanced physiology lecture. When it came to mentioning osmotic pressure and the van ’t Hoff relationship
$$
\pi = ...
-1
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1
answer
34
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What is the ∆H_vap when temperature of a given liquid is equal to the boiling point of the liquid?
What is the $∆H_{vap}$ when temperature of a given liquid is equal to the boiling point of the liquid?
For the other cases ie (i) T>BP, $∆H_{vap}$ > 0 (ii) T<BP, $∆H_{vap}$ < 0
So what ...
0
votes
0
answers
66
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Osmotic Pressure of Aqueous Solution
The osmotic pressure of an aqueous solution at $25$ Celsius is $92.0$ $kPa$. Calculate the boiling point
of the solution. (Assume that the density of the solution is $1.0$ $g/mL$, ignore the mass of ...
0
votes
0
answers
126
views
Why is the Ag+ concentration in a beaker fixed in the reaction between excess AgCl (s) and KI (aq) from the start? [duplicate]
This arises as a sub-question for the following question: Calculate the concentration of I- in a solution obtained by mixing 0.10 M KI with an excess of AgCl(s).
I tried to look at How does addition ...
0
votes
2
answers
2k
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How to know if a reaction forms H3O+ ions or OH- ions? [closed]
How would you know when an acid or base is paired with $\ce{H2O}$ that it will form an $\ce{OH-}$ ion or a $\ce{H3O+}$ ion? I just started the acid and base equilibrium unit, and I'm just confused on ...
3
votes
0
answers
201
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What does isohydric solution mean?
While studying ionic equilibrium, I came across the term "Isohydric Solutions" which is defined as:
Solutions of electrolyte are said to be isohydric if the concentration of the common ion ...
-5
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1
answer
1k
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What is the difference between atom and nucleus? [closed]
Atomic nucleus-The atomic nucleus is the small dense region consisting of protons and neutrons at the center of an atom discovered in 1911 by EARNEST RUTHERFORD. Atoms are made up of a positively ...