All Questions
15
questions
2
votes
4
answers
172
views
How can the Kw of water be constant?
I know in neutral solution, $\ce{[H+]}= \ce{[OH-]}= \pu{1.0 x 10^-7}$.
However, let’s say I add an acid like HCl. This will increase $\ce{[H+]}$, therefore it’s no longer $\pu{1.0 x 10^-7}$, but is ...
3
votes
2
answers
2k
views
Calculate the titer of a solution
I hope this is the right place to ask. We have this exercise without solution
One litre of diluted sodium hydroxide solution (c = 0.15mol/litre) is
to be prepared in the laboratory. The titer from ...
1
vote
0
answers
69
views
Would a container made of sugar eventually dissolve if filled with a sugar-saturated solution of water?
Suppose you had a bottle made of sugar glass, and filled it with water that was already saturated with sugar.
I know that with a fully saturated solution of sugar in water, no additional sugar can ...
0
votes
0
answers
66
views
Osmotic Pressure of Aqueous Solution
The osmotic pressure of an aqueous solution at $25$ Celsius is $92.0$ $kPa$. Calculate the boiling point
of the solution. (Assume that the density of the solution is $1.0$ $g/mL$, ignore the mass of ...
0
votes
0
answers
126
views
Why is the Ag+ concentration in a beaker fixed in the reaction between excess AgCl (s) and KI (aq) from the start? [duplicate]
This arises as a sub-question for the following question: Calculate the concentration of I- in a solution obtained by mixing 0.10 M KI with an excess of AgCl(s).
I tried to look at How does addition ...
0
votes
0
answers
138
views
Problem in the calculation of ionic strength of a solution
Recently I've been trying to answer the question 10-13 (c) of 9th edition of Fundamentals of Analytical Chemistry of Skoog et al. Comparing my answers with the student manual , I realized that my ...
0
votes
4
answers
572
views
How many grams of sodium phosphate must be added to precipitate as much of one ion as possible?
Problem text:
Solid sodium phosphate is slowly added to $\pu{200 mL}$ of a solution containing $\pu{0.002 mol}$ of aluminum chloride and $\pu{0.001 mol}$ of calcium chloride (assuming no volume ...
2
votes
2
answers
2k
views
Why doesn't the solute settle out of a solution, such as brine or sugar water? [closed]
If I have a solution of salt or sugar dissolved in water, the solute will never settle out or "fall to the bottom", no matter low long I wait. Why is that?
Since salt and sugar (in their pure, solid ...
0
votes
0
answers
35
views
How addition of a soluble salt affects equilibrium involving precipitation with a base sharing the same cation?
I have the following reaction at equilibrium:
$$\ce{Ba(NO3)2(aq) + KOH(aq) <=> Ba(OH)2(s) + 2 KNO3(aq)}$$
Will there be a change in the equilibrium if the salt $\ce{KCl}$ is added? Will the ...
3
votes
2
answers
5k
views
Why doesn't a buffer solution change ph(Appreciably?)
Consider a buffer solution containing weak acid $\ce{CH3COOH}$ and its salt $\ce{CH3COONa}$:
\begin{align}
\ce{CH3COOH &<=> CH3COO- + H+} \tag{1}\\
\ce{CH3COONa &-> CH3COO- + Na+} \...
1
vote
1
answer
4k
views
Why are the reactants in the solubility product constant multiplied by their coefficients and raised to the power of their coefficients?
It is probably easiest for me to explain the question in an example. Consider the following chemical reaction:
$\ce{MgF2(s) -> Mg^{2+} (aq) + 2F- (aq)}$
Plugging this into the formula for the ...
3
votes
2
answers
10k
views
About pH of an aqueous solution of SO2
Probably we can have an aqueous solution of $\ce{SO2}$ by dissolving it in water, because we would have an equilibrium between $\ce{SO2(g)}$ and $\ce{SO2(aq)}$:
$$\ce{SO2(g) <=> SO2(aq)}$$
How ...
0
votes
1
answer
2k
views
How to calculate the final concentration of calcium ions from known starting masses of carbonate and calcium ions? [closed]
If $\pu{50.0 mg}$ of $\ce{CO3^2-}$ and $\pu{50.0 mg}$ of $\ce{Ca^2+}$ are present in one liter of water, what will be the final (equilibrium) concentration of $\ce{Ca^2+}$ expressed in moles per ...
0
votes
1
answer
323
views
Ionic equilibrium equation [closed]
What form is the ionic equalibrium equation? I have problem asking for it, but I'be done so many different equalibrium equations that I'm starting to get mixed up on which one is called what... Which ...
0
votes
1
answer
4k
views
Why is the water column empty in ICE table
In the ICE table pure solids and liquids have a value of one in the equilibrium expression but when we create an ICE table, why is the $\ce{H_{2}O}$ column empty? Should it not have a value of one?