All Questions
8
questions
1
vote
3
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994
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Why does equilibrium of ice and water only exist at 273K at normal pressure?
I am a high school student and I am a little confused in the concept of spontaneity of a reaction and how equilibrium works for a reaction, I got some confusions:
Let's take example of freezing of ...
1
vote
1
answer
109
views
Why does Raoult's Law have a weighted sum instead of a direct sum?
I'm fully aware of the various questions asked about Raoult's Law, and I'm asking this after having gone through all of them and not finding a suitable answer to my question.
I have studied, that at a ...
1
vote
1
answer
557
views
Vapour Pressure of A Solution
I study in class 12, and have a doubt in vapour pressure that my school teacher and my friends are not able to clarify.
My doubt is the reason why the partial vapour pressure of each individual ...
6
votes
1
answer
731
views
If volatility depends on intermolecular forces, then why in Raoult's law, two substances have different volatility?
I have a doubt, Ideal solutions are solutions where intermolecular forces between solute-solute and solvent-solvent are nearly equal to solute-solvent. Since intermolecular forces between A-A = B-B, ...
4
votes
3
answers
1k
views
Dynamic equilibrium in unsaturated solutions
One standard definition of equilibrium in beginner chemistry is that for a reversible reaction, (dynamic) equilibrium has been achieved when the rate of the forward and backward reactions are equal. ...
10
votes
2
answers
1k
views
Apparent contradiction in the type of deviation of an ethanol-water mixture
For a mixture of $\ce{EtOH}$ and $\ce{H2O}$: $\Delta H_{\text{mix}} < 0$ (exothermic) and $\Delta V_{\text{mix}} < 0$ (volume contraction). This means that the unlike interactions are stronger ...
4
votes
3
answers
817
views
Finding equilibrium concentrations in solution from initial reagent concentrations and equilibrium constant
We have the following reaction:
$$\ce{A + B<=>2C +D}$$
The initial concentration of $\ce{A}$ and $\ce{B}$ are $\pu{1M}$ each. $K_c$ is $\pu{1.0E8}$. Find the equilibrium concentration of $\ce{A}$...
7
votes
4
answers
2k
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Gibbs Free Energy of Solutes and Solutions
Using the equation $$\ce{CaSO4 (s) <=> Ca^2+ (aq) + SO4^2- (aq)},$$ and $\Delta H/\Delta S$ values, calculate $\Delta G$ at $50~^\circ\mathrm{C}$ when the solution is saturated with $\ce{Ca^2+}$ ...