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3 votes
0 answers
61 views

Is double excitation of nitrogen possible, and would it be able to use it as a central atom in a coordination complex?

I’m 17 and in my 2nd year of high-school (we have it a tad different here in the Czech Republic) and am interested in theoretical chemistry so that’s the explanation of the nature of my question. So, ...
Prokop Hoza's user avatar
-1 votes
1 answer
80 views

Degeneracy of Orbitals

(Sorry, in advance if my question is silly or low quality but I want to ask this to someone.) When an electron enters an orbital, it should technically have an electric Field and also magnetic field(...
Krave37's user avatar
  • 107
13 votes
3 answers
2k views

Do electrons really hang around the electrode while ions go take a swim?

This answer to this post addresses "what happens if you dip a single zinc electrode into some electrolyte solution." It explains that However, though the zinc ion can diffuse through the ...
Buck Thorn's user avatar
  • 22.5k
3 votes
1 answer
71 views

Why are Mo(NR2)3 complexes isolobal with the nitrogen atom in N2

In a Molybdenum complex of the form Mo(NR2)3, the Mo is in the oxidation state of +3, leaving it with 3 d electrons. When combined with an additional 2*3 electrons from the ligands, this leaves it ...
Kirandk's user avatar
  • 422
-2 votes
1 answer
151 views

Colour of coordination compounds due to d-d transition

Hexaaquanickel(II) is green but tetracyanidonickelate(II) is colourless. On internet I found two explanations. One used valence bond theory that claimed there is no excitation of electron in ...
Harjot Dhillon's user avatar
-2 votes
1 answer
48 views

Where does the ionisation energy for a reaction to take place comes from? [closed]

Can anyone tell me exactly what happens during a chemical reaction in terms of ionisation energy? I know that during a reaction there is an exchange of electrons (except for those where electrons are ...
Zane Stockton's user avatar
-3 votes
1 answer
282 views

Why does the oxygen in NaOH (sodium hydroxide) acquire an electron from the sodium if it's going to become unstable and give away the electron? [closed]

Mind you that the oxygen is already stable, having an even number of electrons and protons? Is the oxygen really neutral when it has an even number of electrons and protons?
Phillip Grigsby's user avatar
-1 votes
1 answer
69 views

Refrence on shielding effect vs inter electronic repulsion

Recently I came across a very interesting concept , some scholars were saying that - Shielding accounts just one component (radial) of interelectronic repulsion not complete repulsion Who they are - ...
Bharat Prajapat's user avatar
3 votes
0 answers
471 views

Shielding vs electron-electron repulsion

Example of shielding: (source) The last electron in the 6s subshell of $\ce {Cs}$ is shielded from the nucleus by the inner electrons. Example of electron-electron repulsion: The electron affinity of ...
user avatar
2 votes
0 answers
760 views

AlCl3 and water

While reading Clayden's (et al) Organic Chemistry I stumbled upon a reaction on page 120 that I just fail to wrap my brain around. It describes a reaction of AlCl3 with water and states that, quote, &...
NaughtyPeroxide's user avatar
-1 votes
1 answer
274 views

What does valence electron mean (in the context of spdf orbitals)?

For a little bit of context, my background is in physics and my understanding of chemistry doesn't go past, say, middle school level. Recently, I decided to self-study chemistry and picked up "...
Tham's user avatar
  • 169
-1 votes
1 answer
132 views

Can use lead(II) oxide instead of lead(IV) oxide in car battery?

Question: If the discharge input equation $\ce{PbO2}$ is replaced by $\ce{PbO}$, will the battery still work? I think the product will not be water anymore but hydrogen gas. I am asking this question ...
Maximus Su's user avatar
0 votes
2 answers
247 views

Order of Shielding Effect for orbitals

From what I know Shielding effect is the ability of inner electrons to repel outer electrons and reduce the Nuclear charge felt by the outer electrons and this is caused by electron-electron repulsion....
Bhanu Kiran's user avatar
3 votes
0 answers
101 views

Why is the bond angle of sulphur difluoride greater than that of hydrogen sulphide?

Why is the bond angle of $\ce{SF_2 (98.05^\circ) > SH_2 (92.11^\circ)}$? Isn't this contradicting Bent's rule or otherwise electron repulsion rule ? Fluorine is more electronegative and hence it ...
Ashish's user avatar
  • 1,409
-5 votes
2 answers
1k views

What would happen if the alpha particles directly hit the electrons in the gold foil in Rutherford's experiment? [closed]

What would happen if the alpha particles directly hit the electrons in the gold foil in Rutherford's experiment? Would it get ionized or is there no probability of such a thing happening ?
Ritabanta Ghosh's user avatar

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