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6 votes
2 answers
8k views

Energy of electrons in the same subshell

So I have this quote from wikia (it's similar to my lecture pdf file) but I don't fully understand the statement Although it is commonly stated that all the electrons in a shell have the same ...
PandoraU.U.D's user avatar
3 votes
2 answers
474 views

Is shielding of electrons really best described as shielding or is it really Coulombic repulsion between electrons?

For example, take the 2s electron in lithium - is the reason that it's ionisation energy is lower than would be expected if "shielding" didn't occur at all because the 1s electrons shield the ...
RobChem's user avatar
  • 9,802
20 votes
1 answer
349 views

Is it possible create crystalline solvate of electrons?

Okay, I know that this reads ridiculous insane, but one can obtain solvated electrons by adding sodium metal to liquid ammonia solution. The chemical reaction as written in my inorganic chemistry ...
xyz123's user avatar
  • 547
13 votes
3 answers
56k views

Why is fluorine the most electronegative atom?

It seems related to the atomic size but hydrogen has a smaller atomic size than fluorine. Why is fluorine the most electronegative atom?
bingung's user avatar
  • 456
11 votes
1 answer
2k views

If d-electrons are such poor shielders, why do trends increase more gradually across the d-block than the s or p-block?

If I understand correctly, the shielding effect of d- (and f-) electrons seems to be much poorer than those of s- and p-electrons, due to the fact that they are less penetrating, have less electron ...
VVV's user avatar
  • 155
3 votes
0 answers
475 views

Shielding vs electron-electron repulsion

Example of shielding: (source) The last electron in the 6s subshell of $\ce {Cs}$ is shielded from the nucleus by the inner electrons. Example of electron-electron repulsion: The electron affinity of ...
user avatar
2 votes
1 answer
2k views

Why can't electrons be transferred using hydrogen ions?

Recognizing how oxidation and reduction occurs is essential for analyzing and understanding biochemical reactions. Which of the following methods would NOT be employed in transferring electrons in ...
trav95's user avatar
  • 443
-2 votes
1 answer
153 views

Colour of coordination compounds due to d-d transition

Hexaaquanickel(II) is green but tetracyanidonickelate(II) is colourless. On internet I found two explanations. One used valence bond theory that claimed there is no excitation of electron in ...
Harjot Dhillon's user avatar