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Questions tagged [wavefunction]

A complex scalar field that describes a quantum mechanical system. The square of the modulus of the wave function gives the probability of the system to be found in a particular state. DO NOT USE THIS TAG for classical waves.

29 votes
4 answers
9k views

Continuity & smoothness of wave function

Is there anything physical that enforces the wave function to be $C^2$? Are weak solutions to the Schrödinger equation physical? I am reading the beginning chapters of Griffiths and he doesn't mention ...
countunique's user avatar
  • 1,681
111 votes
15 answers
50k views

About the complex nature of the wave function?

1. Why is the wave function complex? I've collected some layman explanations but they are incomplete and unsatisfactory. However in the book by Merzbacher in the initial few pages he provides an ...
yayu's user avatar
  • 4,842
24 votes
7 answers
15k views

How does the momentum operator act on state kets?

I have been going through some problems in Sakurai's Modern QM and at one point have to calculate $\langle \alpha|\hat{p}|\alpha\rangle$ where all we know about the state $|\alpha\rangle$ is that $$\...
Ruvi Lecamwasam's user avatar
38 votes
3 answers
6k views

The formal solution of the time-dependent Schrödinger equation

Consider the time-dependent Schrödinger equation (or some equation in Schrödinger form) written down as $$ \tag 1 i\hbar \partial_{t} \Psi ~=~ \hat{H} \Psi . $$ Usually, one likes to write that it has ...
Andrew McAddams's user avatar
21 votes
3 answers
2k views

How can I solve this quantum mechanical "paradox"?

Let a (free) particle move in $[0,a]$ with cyclic boundary condition $\psi(0)=\psi(a)$. The solution of the Schrödinger-equation can be put in the form of a plane wave. In this state the standard ...
user32109's user avatar
  • 521
5 votes
1 answer
6k views

Time-independent Schrödinger function: If the potential $V$ is even, then the wave function $\psi$ can always be taken to be either even or odd

I have done the Problem 2.1 in Griffiths' quantum mechanics, and it seems not making sense to me. What if the wave function isn't symmetric at all? Then obviously the proof doesn't work. The ...
Steven's user avatar
  • 61
28 votes
4 answers
22k views

Galilean covariance of the Schrodinger equation

Is the Schrodinger equation covariant under Galilean transformations? I am only asking this question so that I can write an answer myself with the content found here: http://en.wikipedia.org/wiki/User:...
a06e's user avatar
  • 3,732
6 votes
2 answers
3k views

Relation between Wave equation of light and photon wave function?

Suppose in our double slit experimental setup with the usual notations $d,D$, we have a beam of light of known frequency $(\nu)$ and wavelength $(\lambda)$ - so we can describe it as $$ξ_0 = A\sin(kx-\...
Manish Kumar Singh's user avatar
18 votes
2 answers
12k views

When Eigenfunctions/Wavefunctions are real?

When the Hamiltonian is Hermitian(i,e. beyond the effective mass approximation), generally under which conditions the eigenfunctions/wavefunctions are real? What happens in 1D case like the finite ...
Lorniper's user avatar
  • 602
3 votes
2 answers
1k views

Understanding Dirac's notation

Let's say I have eigenstates $|x\rangle$ associated with measurement of position. I know that the eigenstates corresponding to their respective eigenvalues form a basis, let's call it $A$. Now let's ...
Patrick's user avatar
  • 175
19 votes
5 answers
31k views

Normalizing the solution to free particle Schrödinger equation

I have the one dimensional free particle Schrödinger equation $$i\hbar \frac{\partial}{\partial t} \Psi (x,t) = -\frac{\hbar^2}{2m} \frac{\partial^2}{\partial x^2} \Psi (x,t), \tag{1}$$ with ...
Minethlos's user avatar
  • 1,001
17 votes
1 answer
6k views

Bohr-Sommerfeld quantization condition from the WKB approximation

How can one prove the Bohr-Sommerfeld quantization condition $$ \oint p~dq ~=~2\pi n \hbar $$ from the WKB ansatz solution $$\Psi(x)~=~e^{iS(x)/ \hbar}$$ for the Schroedinger equation? With $S$ the ...
Jose Javier Garcia's user avatar
41 votes
5 answers
8k views

Normalizable wavefunction that does not vanish at infinity

I was recently reading Griffiths' Introduction to Quantum Mechanics, and I stuck upon a following sentence: but $\Psi$ must go to zero as $x$ goes to $\pm\infty$ - otherwise the wave function would ...
xletmjm's user avatar
  • 887
40 votes
7 answers
48k views

What exactly is a bound state and why does it have negative energy?

Could you give me an idea of what bound states mean and what is their importance in quantum-mechanics problems with a potential (e.g. a potential described by a delta function)? Why, when a stable ...
Charlie's user avatar
  • 1,104
26 votes
3 answers
15k views

Why the statement "there exist at least one bound state for negative/attractive potential" doesn't hold for 3D case?

Previously I thought this is a universal theorem, for one can prove it in the one dimensional case using variational principal. However, today I'm doing a homework considering a potential like this:$...
an offer can't refuse's user avatar

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