Questions tagged [ionic-compounds]
Compounds in which at least some of bonds have ionic character stronger than covalent or metallic. Many compounds called salts are ionic compounds but not all of them.
484
questions
2
votes
0
answers
55
views
Are Fajans rules relevant to melting and boiling points of alkali metal hydrides?
Among LiH, NaH, KH, RbH, CsH the one with the highest melting point is LiH, and it keeps on decreasing till CsH. The reason for this in my textbook is that the size of cations keeps on increasing down ...
-1
votes
3
answers
107
views
In a crystal of NaCl, how are the NaCl molecules bonded to other NaCl molecules?
I understand that the sodium and chlorine in an individual NaCl molecule are bonded ionically, but how are the molecules in a crystal containing millions of these molecules bonded to eachother?
I'm ...
4
votes
1
answer
257
views
How to Derive the Born-Mayer Equation?
Born-Mayer Equation: $E_{P,min}=-A\frac{N_A|z_1z_2|e^2}{4\pi\varepsilon_0d}(1-\frac{d^*}{d})$
Here is where I have gotten:
$$
E_P=-A\frac{N_A|z_1z_2|e^2}{4\pi\varepsilon_0d}, E_P^*=N_AC'e^{-d/d^*}\\
$$...
5
votes
3
answers
279
views
Does chromium chromate — Cr₂(CrO₄)₃ — exist?
Is it possible to synthesise chromium(III) chromate/dichromate? The intended formulas are $\ce{Cr2(CrO4)3}$ and $\ce{Cr2(Cr2O7)3}$ and they feature both trivalent and hexavalent chromium. However, ...
13
votes
2
answers
2k
views
Could ammonium azanide exist?
In my first high school chemistry class, I misremembered nitrate as being $\ce{NH2-}$, rather than $\ce{NO3-}$, and wrote down a formula for "ammonium nitrate" that was $\ce{NH4NH2}$ (rather ...
0
votes
1
answer
43
views
I have fabricated a starch film impregnated with calcium carbonate, and the film is showing hydrophobic behaviour after addition of calcium carbonate
I have fabricated an extruded starch film, impregnated with calcium carbonate. After addition of calcium carbonate the contact angle of the film has risen suggesting a more hydrophobic surface. I have ...
2
votes
1
answer
159
views
How to name LiN(CF2SO3)2?
I found this compound in the list of inorganic lithium salts from this article on ScienceDirect.
It is said to be of the sulfonate group. Let's focus on the anion alone.
I'm not sure if it can be bis(...
1
vote
1
answer
125
views
Making an UV inactive salt UV active during purification of charged anion with HILIC purification?
In the context of a purification setup I am asking myself the question: Can a UV inactive charged substance made be UV active by a counter ion that absorbs UV light during a column run?
If so, when no ...
0
votes
1
answer
34
views
How to determine the dynamic of progression of two simultaneous precipitation (double replacement) reactions? [duplicate]
We have a solution of mineral water with potassium chromate added to it, and want to titrate the chloride ions in the mineral water. We were told to use silver nitrate for this, which would produce ...
-3
votes
1
answer
78
views
How would the regions of this graph showing percentage of ionic character, be classified? [closed]
Looking here at this website - Omnicalculator, at the section of the website for calculating percentage of ionic character. Omnicalculator - Percentage Ionic Character
They let you choose elements and ...
1
vote
1
answer
105
views
Cesium Chloride Density Gradient Centrifugation and Isotopes
In Cesium Chloride Density Gradient Centrifugation, as used by Meselson and Stahl, Cesium ions can be seen as strongly affected by centrifugation, so much so that they can overcome their ionic bonds ...
-1
votes
1
answer
31
views
How do you perform an ion exchange of a monovalent cation with Br- counterion to a divalent or trivalent anion?
I tried to react an organic compound I have synthesized containing a di-N substituted imidazole bromide salt with Ag3PO4 with water at room temp to try to replace the Bromide with PO4(3-). I dont ...
4
votes
0
answers
316
views
Chemistry of Rutile, CdCl2 and CdI2
During lectures, we were told that 3d transition metal fluorides generally prefer a rutile structure. Chlorides prefer a $\ce{CdCl2}$ structure where $\ce{Cl-}$ adopt a CCP lattice and the metal ...
0
votes
0
answers
47
views
Ionic bond formation [duplicate]
When two separate pieces of sodium chloride crystals are physically put together, no wonder that they will not fuse with each other.
But I don’t understand why. Ionic bonds are described to be non-...
3
votes
1
answer
103
views
Reduction of di-N-substituted imidazole to imidazoline to remove counterion?
I would like to synthesize a di-N-substituted imidazole (compound 4) in its free base form or reduce it to generate an imidazoline (compound 5) to remove the bromide counterion to the imidazole ring.
...
-2
votes
1
answer
76
views
Why is the statement regarding the strength of ionic bonds reasonable? [closed]
In largely ionic compounds (e.g. NaBr and NaI), it seems to be generally true that, the greater the differences of electronegativity between the forming substances (i.e. The compound has more "...
-1
votes
1
answer
442
views
Is mercury(I) chloride ionic or covalent?
Is mercury(I) chloride ionic or covalent? If I look here, I see arguments either way. The article doesn't mention anything about a cation or an anion.
Some might think there's two mercury ions each 1+ ...
-1
votes
1
answer
131
views
Why do samples of ionic compounds break into pieces, but the pieces do not combine into larger samples again?
A distinct property of ionic compounds is that they are brittle. We are taught this is due to the fact that when force is applied to the lattice, ions are shifted, resulting in positive ions repelling ...
8
votes
1
answer
740
views
Is tropylium cyclopentadienide possible?
Has this ever been tried? The respective aromatic ions are readily accessible, e. g., in the form of sodium cyclopentadienide and tropylium bromide. It shouldn't be hard to just combine these two ...
4
votes
1
answer
290
views
What factors cause a few sodium salts to be water-insoluble?
We know that almost all salts with sodium as cation are water-soluble. But there are a few examples where the salt is water-insoluble; such as sodium bismuthate, sodium fluorosilicate, and much more.
...
1
vote
1
answer
157
views
Solubility of SrF2 in aqueous solution of NaF
This might be really simple question but I have no idea how to proceed to solve such kind of question.
The solubility product of $\ce{SrF2}$ in water is $\pu{8E-10}$. Calculate its solubility in 0.1M ...
-2
votes
1
answer
227
views
Calculating salinity from sodium and chloride in water [closed]
let me start by saying that I am definitely no chemist, so this question might (or might not) seem trivial to all you professionals out there.
I have recently found a brand of carbonated water here in ...
4
votes
6
answers
2k
views
Does an ionic bond have a dipole?
Is an ionic compound like NaCl considered a dipole? It has a positive side (Na+) and a negative side (Cl-). Or is it true that an ionic bond does not have a dipole because a dipole is, by definition, ...
2
votes
0
answers
71
views
Crown ether complex formation with cesium carbonate
I am searching for some papers which form complex between crown ether and caesium carbonate. But Most papers only use caesium carbonate as a base in the synthesis of crown ether, not ionic compound ...
0
votes
1
answer
388
views
Magnesium chloride to citrate conversion (reaction/synthesis)
How would one prepare magnesium citrate from magnesium chloride and citric acid? Will it work if I just heat a mixture of magnesium chloride and citric acid in water? I'd expect HCl to vaporize off.
...
4
votes
1
answer
669
views
Why does KCl have FCC structure instead of BCC?
I have this table here.
\begin{array} {|r|r|}\hline \text{Radius Ratio} & \text{Coordination number} & \text{Type of Void} \\ \hline <0.155 & 2 & \text{Linear} \\ \hline 0.155-0....
2
votes
1
answer
138
views
Cannot identify C[Mg+]
I am not able to identify the molecule C[Mg+]. I came across it a number of times in the USPTO-50k dataset, in reactions such as the one shown below:
...
-4
votes
1
answer
237
views
why chemical bond between Na and Cl happens [closed]
We know that if Cl and Na get too close, they produce ionic bonding.
Cl has 17 proton and 17 electrons and is considered stable.
Na has 11 protons and 11 electrons and is considered stable.
I ...
-2
votes
2
answers
300
views
Why is Fe3O4 a non-stoichiometric compound? [closed]
Fe combines with O in a whole number ratio 3:2. Even the ions Fe2+ and Fe3+ are in the ratio 1:2. Then, why Fe3O4 is a non-stoichiometric compound?
-2
votes
1
answer
68
views
Can ionic and/or metallic bonding produce stable long chains? Like polymers, though not necessarily as useful [closed]
Question
Polymers are long chains ⛓️ of covalent bonds.
Can similar structures exist for ionic and/or metallic bonding? They don't have to be as useful.
I know there can be polymers with ionic bonds ...
3
votes
1
answer
332
views
Can I convert copper(II) acetate or carbonate to copper(II) sulfate?
I am a high school student who does chemistry as a hobby, and as such I really don't know very much. I managed to make some copper(II) acetate and copper(II) carbonate, and now I'd like to convert it ...
1
vote
0
answers
231
views
Hannay smith equation derivation
Our chemistry teacher taught us about Hannay smith equation for calculating the percent ionic character. He did not told how that equation was derived. I could not find any satisfactory result from ...
2
votes
1
answer
126
views
Why metal hydrides have low lattice enthalpy
Lattice enthalpy is inversely proportional to the distance between the ions. And the trend of lattice enthalpies is: $\ce{MF>MCl>MBr>MI}$. But why do metal hydrides have lesser lattice ...
1
vote
0
answers
47
views
How to change the counterion of a nucleotide salt?
I need to take the sodium nucleotide salts I have available in my lab and modify them to instead contain some more exotic counterions. Can I do this by binding my nucleotides to a strong anion ...
19
votes
3
answers
4k
views
Are salts (e.g. NaCl) soluble in liquid metals?
I'm curious whether any salt would at all dissolve in a liquid metal, such as gallium, mercury, or some other metal in the liquid phase?
A Google search of "solubility of NaCl in Mercury" ...
0
votes
1
answer
618
views
Why should we not add the H+ ion conc coming from water before calculating pH of acidic/basic solution?
For eg:
If we are calculating pH of the soln of a strong acid, we shall do this:
pH= - log [H+]
Where H+ is the concentration coming from that acid.
Why shall we not add to this concentration, the H+ ...
-2
votes
2
answers
95
views
Are mixtures of finely ground solid fertilizer compounds stable? [closed]
If I had a combination of the following as finely ground powders, would it be relatively stable, or would they react to form other compounds?
Sodium Nitrate
Ammonium Nitrate
Calcium Nitrate
Potassium ...
1
vote
1
answer
2k
views
Compare the covalent character of ZnCl2, CdCl2,HgCl2
I want to know how to arrange the covalent character of ZnCl2, CdCl2, and HgCl2.
By Fajans' rules, We know that a smaller cation equals higher covalent character.
We also know that atomic size ...
2
votes
3
answers
328
views
Why would a metal form an ionic compound with a nonmetal from a lower period?
Take sodium iodide for example. I understand both elements can obtain a full outer shell via the electron transfer. But doesn't the electron move from a lower-energy orbital ($3s$ in sodium) to a ...
1
vote
0
answers
244
views
Confusion related to exception in Fajan's rule (Regarding prediction in solubility of compounds in polar solvents)
My teacher taught us that higher the ionic character in a compound, higher is its solubility in polar solvents like water.
To illustrate this statement, he also gave us the following example-
LiOH< ...
3
votes
1
answer
224
views
Covalent character of bonds in uranium hexafluoride
In one of the questions in a qualifying exam it said that $\ce{UF6}$ is a "covalent compound". This fits the physical properties of the compound well, e.g. low boiling point, existence as ...
1
vote
0
answers
1k
views
How many multivalent elements are there? [closed]
According to this video there are 20 multivalent elements, and from the periodic table, I see 20, but according to multiple websites, including this, it says there are only 5. What am I not ...
0
votes
1
answer
2k
views
How do we know the ionic charge of iron or elements such as iron on the periodic table?
How do we find iron's ionic charge? I was taught that we use roman numerals but I don't see any on the basic periodic table of elements (I'm using this one). So how do we find iron's charge of Fe 2+ ...
-1
votes
1
answer
257
views
Is lead iodide a strong electrolyte?
So, lead iodide is insoluble. I see conflicting answers online. Some say it's a weak electrolyte because it is insoluble, others say it is a strong electrolyte because it is an ionic compound and any ...
1
vote
1
answer
112
views
How do clay particles form a colloidal mixture?
I have been learning about water coagulation in my chemistry textbook. Apparently, before being treated, water has clay particles, primarily silicates and aluminosilicates, which apparently have a ...
-1
votes
1
answer
787
views
Safely removing sodium hypochlorite crystals from hard-to-reach surfaces
I have a small bathing whirlpool which wasn’t used for over ten years. It is built into the ground and I cannot reach the disinfectant container to replace it with a new one. I can access the fill-...
3
votes
0
answers
52
views
How can I transform Thiamine sulfate to Thiamine hydrochloride?
I have got thiamine sulfate and want to have thiamine hydro chloride. Can I obtain it by dissolving thiamine sulfate in water and adding calcium chloride water solution as long as calcium sulfate will ...
0
votes
0
answers
132
views
Does solid sodium hydroxide react with carbon dioxide and air moisture?
I heard a claim in the context of soapmaking that a stray grain of sodium hydroxide will decay into soda ash, i.e. sodium carbonate, on contact with air. This reaction happens in an aqueous solution, ...
0
votes
0
answers
394
views
AlCl3, Al2O3, Al(OH)3. What is more ionic?
I tried with fajans' rules.
First I got AlCl3 and Al2O3. There, because O2- has high negative charge I decided that Al2O3 is less ionic. But my teacher told us that we can get the same thing by ...
2
votes
0
answers
55
views
Why is the Conductivity trend same in fused and in dissolved or aqueous state of ionic compounds?
For an example if we take $\ce{KCl}$ and $\ce{NaCl}$ then I have understood the part where in aqueous state $\ce{Na+}$ becomes bigger than $\ce{K+}$ hence the conductivity reverses but in fused state ...