Let $p = a + b i$ and $q = c + d i$ for some $a, b, c, d \in \mathbb {R}$. Then
$$\begin{align} \frac {p}{p + q} & = \frac {a + b i}{\left( a + c \right) + \left( b + d \right) i} \\ & = \frac {a + b i}{\left( a + c \right) + \left( b + d \right) i} \cdot \frac {\left( a + c \right) - \left( b + d \right) i}{\left( a + c \right) - \left( b + d \right) i} \\ & = \frac {\left[ a \left( a + c \right) + b \left( b + d \right) \right] - \left[ a \left( b + d \right) - b \left( a + c \right) \right] i}{{\left( a + c \right)}^{2} + {\left( b + d \right)}^{2}} \\ & = \frac {\left[ ( {a}^{2} + {b}^{2} ) + \left( a c + bd \right) \right] - \left( a d - b c \right) i}{( {a}^{2} + {b}^{2} + {c}^{2} + {d}^{2} ) + 2 \left( a c + b d \right)}. \end{align}$$
For the sake of compactness, define $r = p / (p + q)$.
$\quad 1)$ Since $\mathfrak {Re} \left( r \right) < 0$, we know $( {a}^{2} + {b}^{2} ) + \left( a c + bd \right) < 0$.
$\quad 2)$ From $\mathfrak {Im} \left( r \right) = 0$, we derive $a d = b c$.
It is given in the question that $a, c \ge 0$.
If $a, c > 0$, then $b d > 0$. Plug this back into $(1)$ and see that $(1)$ will be violated.
If $a = 0$ and $c > 0$, then $b = 0$; however, still, $(1)$ will be violated, so this is impossible.
The same thing will happen if $a > 0$ and $c = 0$.
If $a = c = 0$, then $(2)$ will be satisfied. For $(1)$ to be true, we need ${b}^{2} + b d < 0$. If $b > 0$, then we need $b + d < 0$. If $b < 0$, then we need $b + d > 0$.