Skip to main content

Questions tagged [aqueous-solution]

For questions relating to compounds dissolved in water and resulting reactions and acid-base equilibria.

-4 votes
1 answer
28 views

Water based room spray [closed]

Hello I’m trying to mix essential oils to water and alcohol to create a room spray, unfortunately the oils rise to the surface and clog the atomiser pump. Do you advise to use an emulsifier to the mix?...
Paolo's user avatar
  • 5
4 votes
1 answer
93 views

Why is my Ni or Fe cathode blackening and pores getting blocked during alkaline (6 M KOH) electrolysis?

I am conducting an electrolysis process for hydrogen $(\ce{H2})$ and oxygen $(\ce{O2})$ generation using a $\pu{6 M}$ $\ce{KOH}$ alkaline solution. During the process, I have observed that my cathode ...
Bhavik Modi's user avatar
3 votes
1 answer
52 views

Experiment on pH vs Rate of Electrolysis - what do the results actually say?

My experimental setup looks at using different pH solutions (of $\ce{H2SO4}$ and $\ce{NaOH}$) for electrolysis of water with a Hoffman setup and then measuring the rate of production of gas (note this ...
Eshwar Kolli's user avatar
1 vote
0 answers
41 views

How to dissolve a powdered drug once it has been mixed with water

For a biological experiment I have acquired $\pu{10 mg}$ of CHIR 99021 (laduviglusib). In order to obtain a $\pu{10 mM}$ stock solution, I had to dissolve the powder in $\pu{2.15 mL}$ of dimethyl ...
felbamato's user avatar
2 votes
0 answers
38 views

Salts solubility and speciation calculations using PHREEQC

I am collecting data from literature for CO2 solubility in aqueous solutions. These are usually synthetic brines and are reported as molalities or wt% of salts or salt mixtures (I have NaCl, KCl, ...
Abdeldjalil Latrach's user avatar
0 votes
1 answer
123 views

What reaction takes place when ammonia and sulfur dioxide are introduced into barium chloride solution?

What reaction takes place when gaseous $\ce{NH3}$ and $\ce{SO2}$ are introduced into $\ce{BaCl2}$ solution and an insoluble white solid is produced? I think that the white solid could be $\ce{BaSO4}$ ...
youthdoo's user avatar
  • 133
2 votes
1 answer
65 views

Does solubility product dictate predominant precipitate from the solution with several ionic compounds?

While removing temporary hardness through boiling, magnesium bicarbonate will give $\ce{Mg(OH)2}.$ $\ce{Mg(OH)2}$ predominates over $\ce{MgCO3}$ as the solubility product $K_\mathrm{sp}$ of $\ce{Mg(OH)...
Avaneesh B's user avatar
13 votes
3 answers
2k views

Do electrons really hang around the electrode while ions go take a swim?

This answer to this post addresses "what happens if you dip a single zinc electrode into some electrolyte solution." It explains that However, though the zinc ion can diffuse through the ...
Buck Thorn's user avatar
  • 22.5k
-2 votes
1 answer
85 views

Does Calcium Carbonate dissolve in an aqueous solution of sodium bicarbonate?

A countertop company (Wilsonart) advises the use of sodium bicarbonate to remove limescale (solid calcium carbonate) from the worktop surface. Acidic solutions are contraindicated because the ...
ealdwulf's user avatar
1 vote
1 answer
107 views

Why does balancing the oxidation of dichromate(VI) to chromium(III) require six iron atoms?

The problem: Balance the following chemical equation using oxidation numbers: $$ \ce{Fe^2+ + Cr_2O_7^2- -> Fe^3+ + Cr^3+} $$ What I have tried: $$\ce{\overset{+II}{Fe}^{2+}(aq) + \overset{+VI}{Cr}...
Nora's user avatar
  • 133
1 vote
0 answers
357 views

Who is more polar: acetonitrile or methanol?

According to data dipole moment of acetonitrile is around 4 while that of methanol is 1.7 but is said that acetonitrile is more soluble in non polar solvent that methanol. But shouldn't methanol be ...
Curious's user avatar
  • 21
2 votes
0 answers
63 views

Stability of n-Dodecyl-beta-D-maltoside in buffer solutions for assay experiments

I have a buffer system which contains multiple salts and in addition DTT and n-Dodecyl-beta-D-maltoside. I understand that DTT is hydrolysing quite fast and this component must be used always fresh ...
raptorlane's user avatar
2 votes
2 answers
142 views

In an unsaturated solution, is the product of ions still equal to Ksp?

Suppose I have a solution of a sparingly soluble compound, and consider its solubility in g/L. If I have less g/L of solution than that amount, it means the solution is unsaturated, but what happens ...
odin98's user avatar
  • 67
2 votes
2 answers
314 views

My textbook writes hydronium ion as [H(H2O)]+, is this correct? [closed]

[...] Thus, it bonds to the oxygen atom of a solvent water molecule to give trigonal pyramidal hydronium ion, $\ce{H3O^+}$ $\ce{\{[H (H2O)]^+\}}$ (see box). In this chapter we shall use $\ce{H^+(aq)}$ ...
Hdje's user avatar
  • 127
1 vote
0 answers
31 views

Estimation methods for temperature evolution of a high $\Delta H_{mix}$ dilution ($\ce{KOH}$ in water)

Question up front: Can temperature evolution in solutions be short-hand-estimated by simple state based calculations - with reasonable expectations of precision? (+/- 10° C) I am trying to calculate ...
Stian's user avatar
  • 2,805
-1 votes
1 answer
44 views

Solubility of hydrogen

I'm interested in bacterial fermentation which produces molecular hydrogen as an end product. If bacteria produce molecular hydrogen in solution under anaerobic conditions, does this remain dissolved ...
JadeD's user avatar
  • 7
1 vote
0 answers
70 views

What does it mean for a substance to be "sparingly soluble"?

I have trouble understanding what solubility means. Merriam-Webster defines it as follows: 1 the quality or state of being soluble 2 the amount of a substance that will dissolve in a given amount of ...
odin98's user avatar
  • 67
1 vote
2 answers
443 views

What is the hydrated diameter of a lithium ion?

When salts dissolve in water, the anions, cations, and strongly polar water molecules undergo hydration reactions, resulting in the formation of hydrated ions with a specific number of coordinated ...
陈永曜's user avatar
0 votes
1 answer
473 views

Why does balancing the reduction of dichromate(VI) to chromium(III) require four water molecules among the products?

Problem Balance the following chemical equation using oxidation numbers: $$\ce{Cr2O7^2–(aq) + HNO2(aq) –> Cr^3+(aq) + NO3–(aq)}$$ Solution (in Swedish) $$\ce{\overset{+VI}{Cr}_2O7^2–(aq) + H\...
Nora's user avatar
  • 133
-1 votes
1 answer
66 views

Soluble Ion separation [closed]

Is it possible to separate ions dissolved in solution? I know that the charges have to be balanced, so thinking that maybe it is possible to artificially give that charge? Take for example, sodium ...
Trey Dean's user avatar
1 vote
0 answers
43 views

Increasing energy density for flow batteries with water based electrolyte?

Given a flow battery with a water based electrolyte, would it be possible to increase the energy density of battery by precipitating the redox active species from the anolyte and catholyte solutions? ...
Lance Collins's user avatar
1 vote
3 answers
475 views

Aqueous state on CO2 and O2 in the Photosynthesis Chemical Equation

While reading through a book I came across the equation for photosynthesis: $$ \ce{6CO2(aq) + 12H2O(l) -> C6H12O6(aq) + 6O2(aq) + 6H2O(l)}\tag{1} $$ in the presence of sunlight + chlorophyll. For ...
entropy's user avatar
  • 99
1 vote
0 answers
42 views

Freezing of a beverage

I am trying to generally describe the process of freezing beer and how the different ingredients influence the freezing process. My general approach right now is to observe a beer as 90% water and 10% ...
Maxim's user avatar
  • 11
-2 votes
1 answer
77 views

Mass of gaseous ammonia required to prepare ammonia solution of a given pH

How many grams of gaseous ammonia do you need to make $\pu{200 mL}$ aqueous ammonia solution with $\mathrm{pH} = 11.34?$ As the mole ratio is the same for $\ce{H+}$ and $\ce{NH3},$ $$\ce{NH3 + H+ -&...
Allistor's user avatar
1 vote
0 answers
25 views

visualization problem of dilution of enthalpy $\Delta_{dil} H$ data with different initial concentrations

description I have a question about the $m_f$ vs. $\Delta_{\text{dil}} H$ plot in some experimental studies. For example, the dilution-of-enthalpy data at 300 °C with two initial concetration ($m_i$) ...
acaduck's user avatar
  • 73
-4 votes
1 answer
61 views

Is it possible to make acids and bases in amphiprotic solvents other than water [closed]

In such solvents, could there be chemicals which could donate/accept protons, and if so could their solutions display acidic/basic properties?
Mark R's user avatar
  • 1
2 votes
2 answers
504 views

Changes of colour of sunset yellow in water

I am conducting an experiment on “sunset yellow (FCF)”. Based on my observations, the substance, when in powder form, is bright red in colour (observed with naked eyes). When I dissolve the powder in ...
Freeby Freeby's user avatar
-1 votes
1 answer
94 views

what will happen if we add lithium cobalt oxide into water?is it true that molecule will break and lithium will make LiOH and CoO2? [closed]

I have tried to dissolve powder coated on cathode of lithium ion batteries.
Talha Ahmed's user avatar
1 vote
0 answers
54 views

How can we prevent retrogradation of starch?

Are there any additives which can prevent retrogradation of starch? I have prepared 13% of starch solution along with 2% of NaCl. The results were bit better. The synthesized gel was flowable with ...
Aqib Mehmood's user avatar
-2 votes
1 answer
110 views

Small (personal) scale sea salt production?

I was looking to try to make a small setup for producing small amounts of sea salt. Ideally a series of evaporation chambers, with a heavy brine as the finished product, that could then be baked. May ...
user139996's user avatar

15 30 50 per page