All Questions
Tagged with aqueous-solution experimental-chemistry
61
questions
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visualization problem of dilution of enthalpy $\Delta_{dil} H$ data with different initial concentrations
description
I have a question about the $m_f$ vs. $\Delta_{\text{dil}} H$ plot in some experimental studies.
For example, the dilution-of-enthalpy data at 300 °C with two initial concetration ($m_i$) ...
4
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1
answer
62
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Would having a greater H-bond donor count make a substance more readily enter a twig?
Yes, weird plant scientist asking weird plant questions...
Background:
I am looking at how the twigs of trees absorb water, a poorly understood means by which trees alleviate water stress. Of 4 ...
-4
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4
answers
187
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Drying salts with HCl solution
I'm following a protocol from some old literature (1962), and I want to make sure I'm being safe. It asks you to dissolve some salts in 150 mL water + 25 mL concentrated HCl, then evaporate to dryness ...
1
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0
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284
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What is a suitable process to eliminate an excess of pyridine from an aqueous solution?
I have a reaction in which pyridin is used as a reagent in excess. The resulting product is water soluble and an anion. Pyridinium there will act as a counter ion. Normally, when the product is ...
0
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0
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21
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Dissolution of portlandite, calcite/CaCo3 phase and C-S-H due to high pH
I would like to ask about the possibility of the partial dissolution, over curing time, of portlandite, CaCo3 and C-S-H phases due to high pH (12.5 - 13) of the lime-clay-water systems (lime-...
1
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2
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180
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What is the inconsistency in calculating the differences in Na2O and NaOH in solids (v2)?
(Note that this question has been fully edited for clarity, SE help advised not to delete the question and post another).
Background:
I have a computer model in which I feed it input data from various ...
2
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0
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224
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Why is it recommended to not store commercial sodium silicate solutions in direct sunlight, what are the effects of doing so and can it be modelled?
I regularly purchase aqueous sodium silicate solutions from commercial providers for my studies and note that a storage recommendation for all different grades (i.e. differing $\ce{SiO2 / Na2O}$ ...
4
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Notation for spectral density in experimental community
In an open quantum system setup where the system is coupled to infinite harmonic oscillators as bath (as in the Caldeira leggett model, for example), through the Hamiltonian,
$$H = \frac{\hat{p}^2}{2m}...
0
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62
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Why does the pH of very strong NaOH solutions not make sense? [duplicate]
I'm wondering why the pH of extreme alkaline solutions, such as the case with $\pu{10 M}$ $\ce{NaOH}$ does not make practical sense and I'm wondering why this is the case? Refer to my calculations ...
7
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1
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1k
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Is there a material that ions can pass through but water can’t?
I was wondering whether there is a material that can pass ions (such as the ions existing in seawater) but not water. I am aware that water molecules are smaller, so they can pass through some ...
0
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2
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191
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What might cause overestimated measured pH value of sodium hydroxide solution pumped with carbon dioxide?
I tried an experiment at home where I had a $\ce{CO2}$ tank pumping $\ce{CO2}$ into a solution of $\pu{28 g}$ sodium hydroxide in $\pu{200 ml}$ water. The initial $\mathrm{pH}$ was $11.24.$
I expected ...
-1
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1
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Mixing hydrogen peroxide and sodium hydroxide doesn't lead to sodium peroxide anymore [closed]
I've been using same bottle of hydrogen peroxide and same bottle of 50 % of sodium hydroxide to make sodium peroxide for a month now. You could see the presence of sodium peroxide in the solution ...
1
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1
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2k
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Method to remove impurities from acetaminophen synthesis experiment
I'd like to know about impurities from acetaminophen synthesis experiment. Are there any impurities produced by oxidation of p-aminophenol? If there is any impurity produced by oxidation of p-...
0
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1
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How to make silicic acid, potassium silicate or calcium silicate?
I am a student of tropical agriculture. I am taking the class of agronomic chemistry and plant nutrition. I want to make use of silicate source I have at home for e.g. zeolite, wood ashes, ...
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1
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279
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Aluminum electrodes for NaCl [duplicate]
Upon using aluminium Electrodes for a concentrated solution of NaCl, i conducted electrolysis on the solution for nearly 4-5 hours. There was definitely a gas possibly hydrogen being evolved at the ...