Questions tagged [aqueous-solution]
For questions relating to compounds dissolved in water and resulting reactions and acid-base equilibria.
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Water based room spray [closed]
Hello I’m trying to mix essential oils to water and alcohol to create a room spray, unfortunately the oils rise to the surface and clog the atomiser pump.
Do you advise to use an emulsifier to the mix?...
4
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1
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Why is my Ni or Fe cathode blackening and pores getting blocked during alkaline (6 M KOH) electrolysis?
I am conducting an electrolysis process for hydrogen $(\ce{H2})$ and oxygen $(\ce{O2})$ generation using a $\pu{6 M}$ $\ce{KOH}$ alkaline solution.
During the process, I have observed that my cathode ...
3
votes
1
answer
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Experiment on pH vs Rate of Electrolysis - what do the results actually say?
My experimental setup looks at using different pH solutions (of $\ce{H2SO4}$ and $\ce{NaOH}$) for electrolysis of water with a Hoffman setup and then measuring the rate of production of gas (note this ...
1
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0
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How to dissolve a powdered drug once it has been mixed with water
For a biological experiment I have acquired $\pu{10 mg}$ of CHIR 99021 (laduviglusib). In order to obtain a $\pu{10 mM}$ stock solution, I had to dissolve the powder in $\pu{2.15 mL}$ of dimethyl ...
2
votes
0
answers
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Salts solubility and speciation calculations using PHREEQC
I am collecting data from literature for CO2 solubility in aqueous solutions. These are usually synthetic brines and are reported as molalities or wt% of salts or salt mixtures (I have NaCl, KCl, ...
0
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1
answer
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What reaction takes place when ammonia and sulfur dioxide are introduced into barium chloride solution?
What reaction takes place when gaseous $\ce{NH3}$ and $\ce{SO2}$ are introduced into $\ce{BaCl2}$ solution and an insoluble white solid is produced?
I think that the white solid could be $\ce{BaSO4}$ ...
2
votes
1
answer
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Does solubility product dictate predominant precipitate from the solution with several ionic compounds?
While removing temporary hardness through boiling, magnesium bicarbonate will give $\ce{Mg(OH)2}.$ $\ce{Mg(OH)2}$ predominates over $\ce{MgCO3}$ as the solubility product $K_\mathrm{sp}$ of $\ce{Mg(OH)...
13
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3
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Do electrons really hang around the electrode while ions go take a swim?
This answer to this post addresses "what happens if you dip a single zinc electrode into some electrolyte solution." It explains that
However, though the zinc ion can diffuse through the ...
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1
answer
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Does Calcium Carbonate dissolve in an aqueous solution of sodium bicarbonate?
A countertop company (Wilsonart) advises the use of sodium bicarbonate to remove limescale (solid calcium carbonate) from the worktop surface. Acidic solutions are contraindicated because the ...
1
vote
1
answer
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Why does balancing the oxidation of dichromate(VI) to chromium(III) require six iron atoms?
The problem:
Balance the following chemical equation using oxidation numbers:
$$ \ce{Fe^2+ + Cr_2O_7^2- -> Fe^3+ + Cr^3+} $$
What I have tried:
$$\ce{\overset{+II}{Fe}^{2+}(aq) + \overset{+VI}{Cr}...
1
vote
0
answers
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Who is more polar: acetonitrile or methanol?
According to data dipole moment of acetonitrile is around 4 while that of methanol is 1.7 but is said that acetonitrile is more soluble in non polar solvent that methanol.
But shouldn't methanol be ...
2
votes
0
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Stability of n-Dodecyl-beta-D-maltoside in buffer solutions for assay experiments
I have a buffer system which contains multiple salts and in addition DTT and n-Dodecyl-beta-D-maltoside.
I understand that DTT is hydrolysing quite fast and this component must be used always fresh ...
2
votes
2
answers
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In an unsaturated solution, is the product of ions still equal to Ksp?
Suppose I have a solution of a sparingly soluble compound, and consider its solubility in g/L. If I have less g/L of solution than that amount, it means the solution is unsaturated, but what happens ...
2
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2
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My textbook writes hydronium ion as [H(H2O)]+, is this correct? [closed]
[...] Thus, it bonds to the oxygen atom of a solvent water
molecule to give trigonal pyramidal hydronium ion, $\ce{H3O^+}$ $\ce{\{[H (H2O)]^+\}}$ (see box).
In this chapter we shall use $\ce{H^+(aq)}$ ...
1
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0
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Estimation methods for temperature evolution of a high $\Delta H_{mix}$ dilution ($\ce{KOH}$ in water)
Question up front: Can temperature evolution in solutions be short-hand-estimated by simple state based calculations - with reasonable expectations of precision? (+/- 10° C)
I am trying to calculate ...