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1 vote
2 answers
15k views

Titration of H2SO4 w NaOH: Solving for the molarity of H2SO4?

I am given $\ce{H2SO4}$ in a reaction vessel of about $50~\mathrm{mL}$. I need to solve for the molarity of $\ce{H2SO4}$. A $10~\mathrm{mL}$ sample of $\ce{H2SO4}$ is removed and then titrated with $...
6 votes
1 answer
67 views

How to make a thin layer of crystalline barium titanate on copper substrate?

Is it possible to create a thin $\ce{BaTiO3}$ crystal layer on a copper plate by putting the plate in a beaker, pouring in heated hydrofluoric acid that has been saturated with $\ce{BaTiO3}$ powder ...
2 votes
1 answer
117 views

Difference between change of enthalpy of neutralization between copper and manganese carbonate

I was doing a calorimetry experiment to calculate the change in enthalpy during neutralization reactions between metal carbonates and hydrochloric acid. I experimented with 5 metal carbonates: ...
1 vote
0 answers
36 views

Trends in pKb for both acetic acid and water

I am trying to rationalise a result that I have recently measured in the lab. I'm measuring the pKb of different compounds in anhydrous acetic acid, using the procedure outlined in this paper (https://...
10 votes
4 answers
8k views

What is the real pKa of water?

What is the $\text{p}K_\text{a}$ of water? A simple google search yields the value $15.74$, but this site and this paper say it's $14.0$. According to my understanding, the correct answer should be $...
7 votes
2 answers
642 views

Question about the differences of white and grey NaH properties

We are having some problems with the next reaction in our lab. As you can see, is the sulfonylation of an indole in which we use NaH (60% dispersion in mineral oil) as a base. This reaction goes with ...
2 votes
1 answer
2k views

Does gold always become gold chloride when dissolved with HCl and an oxidizer and can it always be precipitated with sodium metabisulfate?

I tried to extract gold from computer parts by STRIPPING the gold using $\ce{HCl}$ and $\ce{H2O2}$ by dissolving the copper & nickel underneath but i added FAR too much $\ce{H2O2}$ by a stupid ...
-2 votes
3 answers
674 views

Can pure hydronium exist?

Can pure hydronium exist? If not, why not? It seems to me (and I am no chemistry expert) like pure hydronium should have the theoretical maximum acidity or minimum pH that a substance can reach. Can't,...
2 votes
1 answer
272 views

pKa and pKb in solvents other than water

I know that when you have aqueous solutions, then the pKa and the pKb are linked to each other (pKa + pKb = 14). Is there an equivalent relationship between pKa and pKb in non aqueous environments? I'...
1 vote
2 answers
14k views

Titration with Ca(OH)2

In the laboratory, $20.0$ milliliters of an aqueous solution of calcium hydroxide, $\ce{Ca(OH)2}$, was used in a titration. A drop of phenolphthalein was added to it to indicate the end point. The ...
3 votes
2 answers
42k views

Mixing hydrochloric acid and sulphuric acid, both concentrated

In the chemistry lab, I stupidly decided to mix hydrochloric acid and sulphuric acid, both concentrated, in a random ratio, which was about $\pu{50 ml}$. When I poured them in one test tube, the ...
8 votes
1 answer
1k views

The open circuit voltage of a battery: Does it decrease with increase in pH of electrolyte while the voltage across a load increase?

Why does the open circuit voltage of a battery decrease with increase in $\mathrm{pH}$ of electrolyte, but the voltage across a load increase? I tested a cell which had aluminum sulfate as its anode ...
12 votes
1 answer
53k views

How do I calculate the concentration of sulphuric acid by a titration experiment with sodium hydroxide?

In my latest chem lab the objective was to create a primary standard of $\ce{NaOH}$ and use it to determine the concentration of sulfuric acid. The first part of the lab was determine the molarity of ...
0 votes
1 answer
1k views

Steps of crystallization

An excess of copper(II) oxide is added to dilute sulfuric acid to make crystals of hydrated copper(II) sulfate. The processes listed may be used to obtain crystals of hydrated copper(II) sulfate. ...
1 vote
2 answers
1k views

Can ferrous ions exist in an acidic solution?

Can Fe2+ ions exist in an acidic solution or will they always pick up available protons and become Fe3+? My hunch is they can't exist but I'm not really sure. If the latter, does that mean that ...

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