A graph $G$ is said to be perfect if $\chi(H)=\omega(H)$ hold for any induced subgraph $H_i\subseteq G$ (and so for $G$ itself, too)
For maximal planar graphs with connectivity 3, it is easy to construct a class of perfect graphs, such as planar 3-trees. For the connectivity 4, we can also construct infinitely many examples, like graphs in the previous link Are there examples of non-perfect graphs among these graphs (Thanks to Misha Lavrov). However, for the connectivity 5, I have not yet found a corresponding example. Could it be that any 5-connected (maximal) planar graph is not perfect?
The following is SageMath code (Sage 10.3) for searching. I haven't seen it yet:
# Generate 5-connected maximal planar graphs using the Plantri generator
# Note: The value 12 can be adjusted to a higher number for generating larger graphs
gen = graphs.plantri_gen("12 -c5 ")
# Use a generator expression to find the first perfect graph
p = next((g for g in gen if g.is_perfect()), None)
if p is not None:
print(p)
else:
print("No graphs found")