I am not sure if there exists a closed form for
$$I=\int_0^{\pi/2}\frac{x^2\ \text{Li}_2(\sin^2x)}{\sin x}dx$$
which seems non-trivial.
I used the reflection and landen's identity, didn't help much.
In case you are curious how I came up with this integral:
From here we have
$$\arcsin^3(x)=6\sum_{k=1}^\infty\left[\sum_{m=0}^{k-1}\frac{1}{(2m-1)^2}\right]\frac{{2k\choose k}}{4^k}\frac{x^{2k+1}}{2k+1},\quad |x|<1$$
differentiate both sides with respect to $x$ we get
$$\frac{\arcsin^2(x)}{\sqrt{1-x^2}}=2\sum_{k=1}^\infty\left[\sum_{m=0}^{k-1}\frac{1}{(2m-1)^2}\right]\frac{{2k\choose k}}{4^k}x^{2k}$$
use $\sum_{m=0}^{k-1}\frac{1}{(2m-1)^2}=H_{2k}^{(2)}-\frac14H_k^{(2)}$ and replace $x$ by $\sqrt{x}$ we get the form
$$\frac{\arcsin^2(\sqrt{x})}{\sqrt{1-x}}=2\sum_{k=1}^\infty\left[H_{2k}^{(2)}-\frac14H_k^{(2)}\right]\frac{{2k\choose k}}{4^k}x^{k}$$
Divide both sides by $x$ then $\int_0^y$ we have
$$\int_0^y\frac{\arcsin^2(\sqrt{x})}{x\sqrt{1-x}}dx=2\sum_{k=1}^\infty\left[H_{2k}^{(2)}-\frac14H_k^{(2)}\right]\frac{{2k\choose k}}{4^k}\frac{y^{k}}{k}$$
Next, multiply both sides by $-\frac{\ln(1-y)}{y}$ then $\int_0^1$ and use $-\int_0^1 y^{k-1}\ln(1-y)dy=\frac{H_k}{k}$
$$2\sum_{k=1}^\infty\left[H_{2k}^{(2)}-\frac14H_k^{(2)}\right]\frac{{2k\choose k}}{4^k}\frac{H_k}{k^2}=-\int_0^1\int_0^y\frac{\arcsin^2(\sqrt{x})\ln(1-y)}{xy\sqrt{1-x}}dxdy$$
$$=\int_0^1\frac{\arcsin^2(\sqrt{x})}{x\sqrt{1-x}}\left(-\int_x^1\frac{\ln(1-y)}{y}dy\right)dx$$
$$=\int_0^1\frac{\arcsin^2(\sqrt{x})}{x\sqrt{1-x}}\left(\zeta(2)-\text{Li}_2(x)\right)dx$$
$$\overset{\sqrt{x}=\sin\theta}{=}2\int_0^{\pi/2}\frac{x^2}{\sin x}(\zeta(2)-\text{Li}_2(\sin^2x))dx$$
So we have
$$\sum_{k=1}^\infty\left[H_{2k}^{(2)}-\frac14H_k^{(2)}\right]\frac{{2k\choose k}}{4^k}\frac{H_k}{k^2}=\zeta(2)\int_0^{\pi/2}\frac{x^2}{\sin x}dx-\int_0^{\pi/2}\frac{x^2\ \text{Li}_2(\sin^2x)}{\sin x}dx$$
The first integral can be calculated by applying integration by parts then using the fourier series of $\ln(\tan\frac x2)$.
Another question is, clearly the two sums on the LHS are convergent as the denominator blows to infinity much faster than the numerator. But does there exist a closed form for each?
All methods are welcome. Thank you