Another solution to both $\displaystyle \operatorname{Li}_2\left(\frac{1}{2}\right)$ and $\displaystyle \operatorname{Li}_3\left(\frac{1}{2}\right)$
Calculation of $\displaystyle \operatorname{Li}_2\left(\frac{1}{2}\right)$
If we derive and integrate back $\displaystyle \operatorname{Li}_2\left(\frac{x}{1+x}\right)$ from $x=0$ to $x=1$, we have
$$\small \operatorname{Li}_2\left(\frac{1}{2}\right)=\int_0^1 \left(\operatorname{Li}_2\left(\frac{x}{1+x}\right)\right)'\textrm{d}x=\int_0^1\frac{\log(1+x)}{x}\textrm{d}x-\int_0^1\frac{\log(1+x)}{1+x}\textrm{d}x=\frac{\pi^2}{12}-\frac{\log^2(2)}{2},$$
and the calculation is finalized.
Good to mention that the value above can also be extracted immediately from the Dilogarithm Reflection formula which is easy to derive. Of course, one can use directly the strategy used in proving Dilogarithm Reflection formula for getting the desired result.
Calculation of $\displaystyle \operatorname{Li}_3\left(\frac{1}{2}\right)$
If we derive and integrate back $\displaystyle \operatorname{Li}_3\left(\frac{x}{1+x}\right)$ from $x=0$ to $x=1$, and then integrate by parts, we have
$$\operatorname{Li}_3\left(\frac{1}{2}\right)=\int_0^1 \frac{\displaystyle \operatorname{Li}_2\left(\frac{x}{1+x}\right)}{x(1+x)}\textrm{d}x=-\log(2)\operatorname{Li}_2\left(\frac{1}{2}\right)-\int_0^1 \frac{\displaystyle \log(1+x)\log\left(\frac{x}{1+x}\right)}{x(1+x)}\textrm{d}x$$
$$=-\log(2)\operatorname{Li}_2\left(\frac{1}{2}\right)-\frac{1}{3}\log^3(2)-\underbrace{\int_0^1\frac{\log(x)\log(1+x)}{x}\textrm{d}x}_{\displaystyle -3/4\zeta(3)}+\frac{1}{2}\underbrace{\int_0^1\frac{\log^2(1+x)}{x}\textrm{d}x}_{\displaystyle 1/4\zeta(3)}$$
$$=\frac{7 }{8}\zeta (3)-\frac{1}{2}\log (2)\zeta(2)+\frac{1}{6}\log ^3(2),$$
where the first of the remaining integrals can be approached with polylogarithms or geometric series, and the second one can be approached easily with algebraic identities.
A first note: A nice approach (and possibly unexpected) involving a form of Beta function to the integral $\displaystyle \int_0^1\frac{\log^2(1+x)}{x}\textrm{d}x$ may be found in the book, (Almost) Impossible Integrals, Sums, and Series, pages $72$-$73$.
A second note: From the solution in the book (see previous note), we immediately have that
$$\int_0^1\frac{\log^2(1+x)}{x}\textrm{d}x-\int_0^1\frac{\log(x)\log(1+x)}{x}\textrm{d}x=\int_0^1 \frac{\log(x)\log(1-x)}{x}\textrm{d}x,$$
which can be perfectly used in the solution above to avoid the algebraic identities (if we want to).
A third note: Let's recall a well-known result in the work with polylogarithms,
$$\int_0^x \frac{\log^2(1+t)}{t} \textrm{d}t$$
$$=\log(x)\log^2(1+x)-\frac{2}{3}\log^3(1+x)-2\log(1+x) \operatorname{Li}_2\left(\frac{1}{1+x}\right)-2 \operatorname{Li}_3\left(\frac{1}{1+x}\right),$$
found in the famous book Polylogarithms and Associated Functions by Leonard Lewin.
The nice thing about this method (involving the present generalization) is that in the right-hand side we get the desired trilogarithmic value with the opposite sign which assures the extraction, avoiding again the use of algebraic identities. The result is also met in the book, (Almost) Impossible Integrals, Sums, and Series, Section 1.4, page $3$.
A fourth note: perhaps no need to mention the third identity in $(1)$ here http://mathworld.wolfram.com/Trilogarithm.html
A fifth note: A fancy way of extracting the value $\displaystyle \operatorname{Li}_3\left(\frac{1}{2}\right)$ is based upon the identity
$$\small\int_0^1 \frac{\log (x) \log (1-x)}{1-a x} \textrm{d}x=\frac{\pi^2}{6}\frac{ \log (1-a)}{a}+\frac{1}{6}\frac{\log ^3(1-a)}{a}+\frac{1}{a}\operatorname{Li}_3(a)-\frac{1}{a}\operatorname{Li}_3\left(\frac{a}{a-1}\right), \ a<1,$$
used in this solution https://math.stackexchange.com/q/3503196. Setting $a=-1$ everything becomes clear in the right-hand side, and in the left-hand side the integral we have to deal with is already calculated elegantly in the paper A note presenting the generalization of aspecial logarithmic integral, that is
$$\int_0^1 \frac{\log(x)\log(1-x)}{1+x}\textrm{d}x=\frac{13}{8}\zeta(3)-\frac{3}{2}\log(2)\zeta(2).$$
From another point of view, if we assume knowledge of the value of $\displaystyle \operatorname{Li}_3\left(\frac{1}{2}\right)$, we get another way of calculating the previously mentioned integral.