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Questions tagged [aqueous-solution]

For questions relating to compounds dissolved in water and resulting reactions and acid-base equilibria.

-4 votes
1 answer
26 views

Water based room spray [closed]

Hello I’m trying to mix essential oils to water and alcohol to create a room spray, unfortunately the oils rise to the surface and clog the atomiser pump. Do you advise to use an emulsifier to the mix?...
Paolo's user avatar
  • 5
4 votes
1 answer
92 views

Why is my Ni or Fe cathode blackening and pores getting blocked during alkaline (6 M KOH) electrolysis?

I am conducting an electrolysis process for hydrogen $(\ce{H2})$ and oxygen $(\ce{O2})$ generation using a $\pu{6 M}$ $\ce{KOH}$ alkaline solution. During the process, I have observed that my cathode ...
Bhavik Modi's user avatar
3 votes
1 answer
51 views

Experiment on pH vs Rate of Electrolysis - what do the results actually say?

My experimental setup looks at using different pH solutions (of $\ce{H2SO4}$ and $\ce{NaOH}$) for electrolysis of water with a Hoffman setup and then measuring the rate of production of gas (note this ...
Eshwar Kolli's user avatar
1 vote
0 answers
39 views

How to dissolve a powdered drug once it has been mixed with water

For a biological experiment I have acquired $\pu{10 mg}$ of CHIR 99021 (laduviglusib). In order to obtain a $\pu{10 mM}$ stock solution, I had to dissolve the powder in $\pu{2.15 mL}$ of dimethyl ...
felbamato's user avatar
2 votes
0 answers
37 views

Salts solubility and speciation calculations using PHREEQC

I am collecting data from literature for CO2 solubility in aqueous solutions. These are usually synthetic brines and are reported as molalities or wt% of salts or salt mixtures (I have NaCl, KCl, ...
Abdeldjalil Latrach's user avatar
0 votes
1 answer
121 views

What reaction takes place when ammonia and sulfur dioxide are introduced into barium chloride solution?

What reaction takes place when gaseous $\ce{NH3}$ and $\ce{SO2}$ are introduced into $\ce{BaCl2}$ solution and an insoluble white solid is produced? I think that the white solid could be $\ce{BaSO4}$ ...
youthdoo's user avatar
  • 133
2 votes
1 answer
64 views

Does solubility product dictate predominant precipitate from the solution with several ionic compounds?

While removing temporary hardness through boiling, magnesium bicarbonate will give $\ce{Mg(OH)2}.$ $\ce{Mg(OH)2}$ predominates over $\ce{MgCO3}$ as the solubility product $K_\mathrm{sp}$ of $\ce{Mg(OH)...
Avaneesh B's user avatar
13 votes
3 answers
2k views

Do electrons really hang around the electrode while ions go take a swim?

This answer to this post addresses "what happens if you dip a single zinc electrode into some electrolyte solution." It explains that However, though the zinc ion can diffuse through the ...
Buck Thorn's user avatar
  • 22.5k
-2 votes
1 answer
84 views

Does Calcium Carbonate dissolve in an aqueous solution of sodium bicarbonate?

A countertop company (Wilsonart) advises the use of sodium bicarbonate to remove limescale (solid calcium carbonate) from the worktop surface. Acidic solutions are contraindicated because the ...
ealdwulf's user avatar
1 vote
1 answer
106 views

Why does balancing the oxidation of dichromate(VI) to chromium(III) require six iron atoms?

The problem: Balance the following chemical equation using oxidation numbers: $$ \ce{Fe^2+ + Cr_2O_7^2- -> Fe^3+ + Cr^3+} $$ What I have tried: $$\ce{\overset{+II}{Fe}^{2+}(aq) + \overset{+VI}{Cr}...
Nora's user avatar
  • 133
1 vote
0 answers
352 views

Who is more polar: acetonitrile or methanol?

According to data dipole moment of acetonitrile is around 4 while that of methanol is 1.7 but is said that acetonitrile is more soluble in non polar solvent that methanol. But shouldn't methanol be ...
Curious's user avatar
  • 21
2 votes
0 answers
62 views

Stability of n-Dodecyl-beta-D-maltoside in buffer solutions for assay experiments

I have a buffer system which contains multiple salts and in addition DTT and n-Dodecyl-beta-D-maltoside. I understand that DTT is hydrolysing quite fast and this component must be used always fresh ...
raptorlane's user avatar
2 votes
2 answers
141 views

In an unsaturated solution, is the product of ions still equal to Ksp?

Suppose I have a solution of a sparingly soluble compound, and consider its solubility in g/L. If I have less g/L of solution than that amount, it means the solution is unsaturated, but what happens ...
odin98's user avatar
  • 67
2 votes
2 answers
313 views

My textbook writes hydronium ion as [H(H2O)]+, is this correct? [closed]

[...] Thus, it bonds to the oxygen atom of a solvent water molecule to give trigonal pyramidal hydronium ion, $\ce{H3O^+}$ $\ce{\{[H (H2O)]^+\}}$ (see box). In this chapter we shall use $\ce{H^+(aq)}$ ...
Hdje's user avatar
  • 127
1 vote
0 answers
30 views

Estimation methods for temperature evolution of a high $\Delta H_{mix}$ dilution ($\ce{KOH}$ in water)

Question up front: Can temperature evolution in solutions be short-hand-estimated by simple state based calculations - with reasonable expectations of precision? (+/- 10° C) I am trying to calculate ...
Stian's user avatar
  • 2,805

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