Sharing a drive with across a network is easy with windows 7. First, hit WindowsKey + E to open an explorer window. Right-click on the drive you want to share, and Share With > Advanced Sharing
Click the Advanced Sharing button, then name the drive as you see fit. You will also need to assign permissions, which can be done granularly, or you can use the user 'Everyone' and its all access for all.
Click OK or Apply to save your changes and your drive should be available on the network by going to \\Your_PC_Name\Shared_Folder_Name
Keep security in mind if you share this network with other people. If you give all access rights to everyone, then anyone can delete/alter files. However if you give named access to individuals, you may not be able to access the share from a device such as a phone.
A final note, if you end the share name with a dollar sign ($), then the share will be hidden from users casually browsing, and they will only find it by explicitly typing in the name of the share.
Also see directions from Microsoft