This post here:
New motherboard or new PC to gain access to RAID drives
Suggests that if I am using a software raid, I can swap out the motherboard with no issue as long as I am using the same OS.
This post here Defines how to detect whether or not your raid is software raid or not: http://michaelsanford.com/how-can-i-tell-if-im-using-hardware-or-software-raid/
Which I have:
I believe I should be safe to install the new motherboard and raid card (New motherboard lacks enough sata ports) due to it being a software raid, I just wanted to clarify before attempting due to the nature of the raid being a nas raid.