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Questions tagged [polymers]

Polymers is concerned with the physical properties of individual macromolecules. For questions regarding bulk behavior of ensembles of polymers, the [condensed-matter] tag may be more appropriate.

2 votes
1 answer
165 views

Can anyone explain this condensation pattern?

What is the hair-like "polymer" that condenses on the caps of the plastic cell vial? Inside vial are cells in a mixture of FBS and DMSO. The vials were frozen slowly in a special isopropanol-filled ...
user36181's user avatar
1 vote
1 answer
45 views

How can the presence of a solvent be included in a polymer bead-spring model?

I have a bead-spring model of a polymer melt and I would like to simulate what happens when a solvent is added to the system. The most direct way to do this would be to add solvent particles into the ...
user668074's user avatar
0 votes
1 answer
114 views

Pressurizing with nitrogen vs vacuum? [closed]

pressurizing with vacuum causes volatilization of liquid.
Betsy's user avatar
  • 325
7 votes
1 answer
652 views

Molecular Dynamics Software for Coarse Grained Polymers

I am looking around for MD software that I can use to simulating polymers and I can't decide which software I should use. I would like to simulate the swelling of crosslinked polymers, and I would ...
1 vote
1 answer
247 views

Standard linear solid model - dashpot "short out" at $t=0$

My professor said that at $t=0$ the dashpot in standard linear solid is "short out". Why? I know that the force of dashpot is ($u$ is the dislplacement): $$F_{\eta}=\eta \space \frac{du}{dt}.$$
Federica Guidotti's user avatar
-1 votes
1 answer
303 views

Stress relaxation time scale [closed]

What is the definition and physical meaning of "stress relaxation time scale" in (non-Newtonian) fluids?
Mohamed Ouda's user avatar
1 vote
0 answers
33 views

Electret analog of Curie temperature

If you heat a permanent magnet above its Curie temperature then individual dipoles re-align to cancel each other out and it loses its strength. An electret is the electrical analog of a permanent ...
EngrStudent's user avatar
0 votes
1 answer
4k views

What do people mean with "per unit volume" in polymer solutions theory?

I am reading Modern Theory of Polymer Solutions by Hiromi Yamakawa and in the context of the virial expansion the following puzzles me a bit: "...expanded in terms of solute concentration $c$ (in ...
Asking Questions's user avatar
1 vote
1 answer
92 views

Scaling argument for friction force on a chain in shear flow

In her paper entitled "Deformations of One Tethered Chain in Strong Flows", the author makes the argument that given a shear flow velocity $v_x(y)=sy$ in a solution of viscosity $\eta$, and a tethered ...
KBriggs's user avatar
  • 439
7 votes
1 answer
3k views

Partition function for polymer chain

Supposing that I have linear chain with polymer of $N$ identical particles (interacting harmonically with adjacent particle) with position of first and last particle fixed, how do I find the partition ...
S L's user avatar
  • 1,541
4 votes
2 answers
110 views

Is a folded protein's conformation subject to thermal fluctuations?

In biology class we learn that proteins are folded, and that the shape the protein takes affects its bioactivity. Typically we don't go much further into protein shape from that, at least not at the ...
Dargscisyhp's user avatar
  • 5,329
7 votes
1 answer
2k views

Hindered rotation model for flexible polymers: deriving the Flory characteristic ratio

In the hindered rotation model we assumes constant bond angles $\theta$ and lengths $\ell$, with torsion angles between adjacent monomers being hindered by a potential $U(\phi_i)$. In Rubinstein's ...
KBriggs's user avatar
  • 439
-1 votes
1 answer
3k views

Difference in viscosity-concentration and reduced viscosity-concentration graphs

I prepared 3 different polymer solutions with varying concentration of 100, 50 and 25 ppm in order to measure their viscosity . When I plot concentration vs viscosity graph in the excel, I have a ...
Thomson1's user avatar
1 vote
2 answers
2k views

Why polymeric solids are said to be intermediate between crystalline solids and amorphous solids?

Crystalline solids have ordered arrangement and amorphous solids do not. Polymeric solids are simply formed by the joining of some monomeric units. It has nothing to do with ordered or not ordered ...
Emma's user avatar
  • 107
1 vote
1 answer
98 views

Effective length factor of a polymer in solution

If one wants to calculate the force needed to buckle a polymer in solution with Euler buckling, what would the effective length factor be? The polymer is free to move and rotate in solution as it sees ...
Breaking Bioinformatics's user avatar

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