Have I shown correctly which properties the relation fulfills?
$$aRb \text{ iff } a + 2b \equiv 0 \pmod 3$$
$(1)$ Reflexivity
Set $b=a$
$a + 2a = 3a \equiv 0 \pmod 3$
Hence, the relation is reflexive.
$(2)$ Symmetry
(*) $a + 2b \equiv 0 \pmod 3$
(**) $b + 2a \equiv 0 \pmod 3$
Assuming (*) and (**) are true, the sum must also be divisible by three (if * and ** were not satisfied, the sum would lie in another congruence class):
$a + b + 2a + 2b = (a+b) + 2(a+b) \equiv 0 \pmod 3$
Set $a+b=c$
Then $c + 2c = 3c \equiv 0 \pmod 3$
Hence, the relation is symmetric.
$(3)$ Antisymmetry
Counterexample: $a=4, b = -5$
$4 + 2*(-5)=-6 \equiv 0 \pmod 3\implies aRb$
$-5 + 2*4 = 3 \equiv 0 \pmod 3\implies bRa$
But $a\neq b$, hence the relation is not antisymmetric.
$(4)$ Transitivity
$a + 2b \equiv 0 \pmod 3$
$b + 2c \equiv 0 \pmod 3$
$a + b + 2(b+c) \equiv 0 \pmod 3$
$(a + 2b) + b + 2 c \equiv 0 \pmod 3$
Hence, $(a+2c)\equiv0 \pmod 3 \implies $ relation is transitive.