Let $a(n)$ be the number of sets that can be built using length-$n$ combination of either a commas and braces. Here's a manual calculation of $a(n)$ for $0<n<13$ (duplicate sets have been removed)
a(1) = 0
a(2) = 1 {}
a(3) = 0
a(4) = 1 {{}}
a(5) = 0
a(6) = 1 {{{}}}
a(7) = 1 {{},{}}
a(8) = 1 {{{{}}}}
a(9) = 2 {{{},{}}} {{{}},{}}
a(10) = 2 {{{{{}}}}} {{},{},{}}
a(11) = 4 {{{{}}},{}} {{{{},{}}}} {{{{}},{}}} {{{}}, {{}}}
a(12) = 3 {{...}} {{{},{},{}}} {{{},{}},{}}
With the help of some crappy Python program I wrote, I extended the sequence further:
a(13) = 7
a(14) = 7
a(15) = 11
a(16) = 16
a(17) = 18
a(18) = 30
a(19) = 34
a(20) = 56
a(21) = 65
a(22) = 102
a(23) = 134
a(24) = 183
a(25) = 275
a(26) = 348
a(27) = 544
a(28) = 699
a(29) = 1057
a(30) = 1441
a(31) = 2062
a(32) = 2982
As of the time of writing, there's no OEIS page for this sequence. Is there a closed-form formula for $a(n)$? If not, is there at least some good approximation?