Wikipedia gives the following definition of positive operator-valued measure (POVM):
A POVM on a measurable space $(X,M)$ is a function $F$ defined on $M$ whose values are bounded non-negative self-adjoint operators on a Hilbert space $\mathcal{H}$ such that $F(X) = 1_\mathcal{H}$ and for every $\psi \in \mathcal{H}$ the map $E \mapsto \langle F(E) \psi , \psi \rangle$ is a non-negative countably additive measure on $M$.
When the set of outcomes $X$ is finite and/or the Hilbert space has finite dimension, a simpler definition can be easily found in standard textbooks, but in the general case none of the books I've checked (on quantum mechanics, functional analysis or $C^*$-algebras) contains a definition. Do you have a reference, other than Wikipedia, for an equivalent definition of POVM?