Let $(G, \cdot)$ be a finite group of order $n$. Consider the map:
$$G \to G, g \mapsto g^k$$
for $k$,$n$ coprime. This is injective, but generally not a homomorphism.
Define a new group $G_k = (G,\circ)$ by:
$$g \circ h = (g^k h^k)^{\frac{1}{k}}$$
where naturally $g \mapsto g^{\frac{1}{k}}$ is the (well-defined) inverse of $g \mapsto g^k$. It is easily verified that this gives a valid group operation.
Question: Is it true that $G \cong G_k$ for all $k$ coprime to $n$?
The map is clearly an isomorphism if $G$ is abelian (or more generally, $k$-abelian). Also, note that the order of any $g \in G_k$ is the same as the order of $g \in G$. Thus, $G, G_k$ have the same order sequence, so according to this answer, any counterexample must have $n \ge 16$, and I am not very familiar with these groups. (But I do not expect the statement to be true.)
I also noticed that if $G \sim H$ when $H \cong G_k$ for some $k$ (coprime to $|G|$), then $\sim$ is an equivalence relation.