There is an isomorphism of abelian groups $\operatorname{Hom}_{\mathbb{Z}} (\mathbb{Q}, \mathbb{Q}/\mathbb{Z}) \cong \mathbb{R}$, a proof is based on three observations:
$\operatorname{Hom}_{\mathbb{Z}} (\mathbb{Q}, \mathbb{Q}/\mathbb{Z}) $ is torsion free.
$\operatorname{Hom}_{\mathbb{Z}} (\mathbb{Q}, \mathbb{Q}/\mathbb{Z}) $ is a divisible abelian group.
Hence $\operatorname{Hom}_{\mathbb{Z}} (\mathbb{Q}, \mathbb{Q}/\mathbb{Z}) $ is a vector space over $\mathbb{Q}$ and it has the same cardinality as $\mathbb{R}$, hence there is an isomorphism of $\mathbb{Q}$-vector spaces $\operatorname{Hom}_{\mathbb{Z}} (\mathbb{Q}, \mathbb{Q}/\mathbb{Z}) \cong \mathbb{R}$.
This proof is indirect. If we think about elements of $\mathbb{R}$ as classes of Cauchy sequences of elements of $\mathbb{Q}$, can we directly interpret such sequence as an element in $\operatorname{Hom}_{\mathbb{Z}} (\mathbb{Q}, \mathbb{Q}/\mathbb{Z})$?