Here's my approach.
Since $ a^5 < 5, a<\sqrt[5]{5} $
By density of rational number, there must be integer $m$ and natural number $n$ such that
$ a< \frac{m}{n} < \sqrt[5]{5}$
If I let $b= \frac{m}{n} $, then $ a<b$ and $ b<\sqrt[5]{5} $
Since, $ b< \sqrt[5]{5}$, $ b^5 < 5 $, therefore there exists $b$ such that $a<b$ and $b^5<5$
Is there anything that I should fix or add? I wonder if I have to show that there exists real number $a$ such that $a^5<5$.