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\begin{align}&\color{#66f}{\large%
\sum_{m\ =\ 0}^{n - 1}{2 \over n\pars{2n - 2m - 1}}}
=-\,{1 \over n}\sum_{m\ =\ 0}^{n - 1}{1 \over m - n + 1/2}
\\[5mm]&=-\,{1 \over n}\sum_{m\ =\ 0}^{\infty}
\pars{{1 \over m - n + 1/2} - {1 \over m + 1/2}}
=-\sum_{m\ =\ 0}^{\infty}{1 \over \pars{m + 1/2}\pars{m - n + 1/2}}
\\[5mm]&=-\,{\Psi\pars{1/2} - \Psi\pars{1/2 - n}\over
1/2 - \pars{1/2 - n}}
={\Psi\pars{1/2 - n} - \Psi\pars{1/2} \over n}
\end{align}
where $\ds{\Psi}$ is the Digamma function.
Moreover, $\ds{\Psi\pars{x} = H_{x - 1} - \gamma}$. $\ds{H_{x}}$ is the
Harmonic Number and
$\ds{\gamma}$ is the Euler-Mascheroni constant. Then,
$$
\color{#66f}{\large%
\sum_{m\ =\ 0}^{n - 1}{2 \over n\pars{2n - 2m - 1}}}
=\color{#66f}{\large{H_{-1/2 - n} - H_{-1/2} \over n}}
$$
Another useful relation is found with:
\begin{align}
\Psi\pars{\half - n} - \Psi\pars{\half}&=
\braces{\Psi\pars{\half + n} + \pi\cot\pars{\pi\bracks{n + \half}}}
-\bracks{-\gamma - 2\ln\pars{2}}
\\[5mm]&=\Psi\pars{{3 \over 2} + n} - {1 \over n + 1/2} + \gamma + 2\ln\pars{2}
\\[5mm]&=H_{n + 1/2} - {2 \over 2n + 1} + 2\ln\pars{2}
={\pars{2n + 1}\bracks{H_{n + 1/2} + 2\ln\pars{2}} - 2 \over 2n + 1}
\end{align}
such that
$$
\color{#66f}{\large%
\sum_{m\ =\ 0}^{n - 1}{2 \over n\pars{2n - 2m - 1}}}
=\color{#66f}{\large{\pars{2n + 1}\bracks{H_{n + 1/2} + 2\ln\pars{2}} - 2
\over n\pars{2n + 1}}}
$$