I have a small DC motor acting as a generator, spinning at 500RPM. From it, I get 1V with ½V ripple, which a 1000uF electrolytic capacitor smooths nicely.
I may wish to drive the motor in reverse, getting -1V.
To do smoothing in either situation I'd need a 1000uF unpolarised capacitor, which as far as I know you can't get.
Is there another way?