Unanswered Questions
753 questions with no upvoted or accepted answers
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Which potentials are suitable for molecular dynamics simulation of simple explicit solvents?
Which potentials (force fields) are suitable for adequately simulating (mixtures of) explicit solvents? Interesting rheological properties include viscosity, surface tension, heat capacity.
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Cobalt Chloride in various solvent/water mixtures - tested
In a recent post the solvatochromic behaviour of cobalt chloride in acetone was discussed. There were some ideas how the acetone might influence the ratio between the blue $\ce{[CoCl4]^2-}$ and the ...
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What exactly is an "electron-sponge"?
What exactly an "electron-sponge" [behavior/action/property/system] nickname is, and what makes a material an "electron-sponge" (preferably, quantitatively)?
From what I found, it's typically a ...
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Removal of nickel plating on MgB2 without damaging the boride?
I need to remove a nickel plating of a MgB2 wire without causing damage to the MgB2. I felt that electrolysis is the best method but I do not know what electrolyte to use for this. I also need to coat ...
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Does phosphoric acid remove stainless steel electropolished layer?
Electropolished stainless steel has a high corrosion resistance due to the oxide film that is created during electropolishing. The film mainly consist of chromium(III) oxide.
Phosphoric acid is ...
6
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Are all humectants sticky?
While using a topical lotion based on ethanol, water and propylene glycol, I noticed that it becomes sticky while drying. Propylene glycol is a humectant and is used for this purpose in ...
6
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Why is supersaturated sodium acetate so (meta)stable?
Sodium acetate is a common example used in general chemistry lectures to illustrate the idea of supersaturation, and that precipitation of a supersaturated solution can be initiated by a seed crystal. ...
6
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Correct Definition of Absolute Electrode Potential
I thought absolute electrode potential is Galvani potential difference at the interface. However, it is given by following equation in John Bockris - Modern Electrochemistry (Ref.1): $$ E^M \mathrm{(...
6
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775
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How can copper(II) sulfate crystallize outside a glass vial?
I'm making copper sulfate crystals in glasses. Within a few weeks, the copper sulfate seems to crystallize both inside and outside the glass:
(A few weeks after making a new solution)
(Yet another ...
6
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154
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Dissolving ability of octane vs nonane on neoprene
I have been working with straight chain octane and nonane. The neoprene seals in some parts of the apparatus are allegedly far more vulnerable to the deleterious effects of octane than nonane - why? [...
6
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How to dissolve a strong resin in difficult situation?
The resin is made up from two components:
Component A: silicic acid, sodium salt (less than 10% sodium silicate)
Component B: Diphenylmethane-4,4'-Diisocyanate, isomers and homologs (MDI,Polymer-MDI)...
5
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How to remove glass shards out of a tiny hole to fit capillary tube?
This is oddly specific, but I am having trouble making the setup work for my electrochemical cell. We're doing Scanning Electrochemical Cell Microscopy (SECCM)* and the device has a capillary tube fit ...
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Regarding the standard reduction potential and electrolyte/solid interface
I am modelling lithium-sulfur batteries ($\ce{LiS}$ batteries) and a strange phenomenom happens during charge, named infinite charging, which I show below:
The factor $f_\mathrm{C}$ that appears in ...
5
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232
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Is there an alternative to potassium iodide as an electrolyte in dye-sensitized solar cells?
I'm helping my son build a dye-sensitized solar cell for his school project according to the directions on homemade-circuits.com. We're currently in the process of gathering the necessary materials. ...
5
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Anomaly in Faraday's constant measurements
I was reading someone's biography, where the writer stated his early interest in Faraday's constant measurements (this is set six decades ago). My understanding was that Faraday constant is a true ...