Skip to main content

Unanswered Questions

753 questions with no upvoted or accepted answers
10 votes
0 answers
109 views

Which potentials are suitable for molecular dynamics simulation of simple explicit solvents?

Which potentials (force fields) are suitable for adequately simulating (mixtures of) explicit solvents? Interesting rheological properties include viscosity, surface tension, heat capacity.
9 votes
0 answers
622 views

Cobalt Chloride in various solvent/water mixtures - tested

In a recent post the solvatochromic behaviour of cobalt chloride in acetone was discussed. There were some ideas how the acetone might influence the ratio between the blue $\ce{[CoCl4]^2-}$ and the ...
8 votes
0 answers
392 views

What exactly is an "electron-sponge"?

What exactly an "electron-sponge" [behavior/action/property/system] nickname is, and what makes a material an "electron-sponge" (preferably, quantitatively)? From what I found, it's typically a ...
8 votes
0 answers
102 views

Removal of nickel plating on MgB2 without damaging the boride?

I need to remove a nickel plating of a MgB2 wire without causing damage to the MgB2. I felt that electrolysis is the best method but I do not know what electrolyte to use for this. I also need to coat ...
7 votes
0 answers
516 views

Does phosphoric acid remove stainless steel electropolished layer?

Electropolished stainless steel has a high corrosion resistance due to the oxide film that is created during electropolishing. The film mainly consist of chromium(III) oxide. Phosphoric acid is ...
6 votes
0 answers
209 views

Are all humectants sticky?

While using a topical lotion based on ethanol, water and propylene glycol, I noticed that it becomes sticky while drying. Propylene glycol is a humectant and is used for this purpose in ...
6 votes
0 answers
164 views

Why is supersaturated sodium acetate so (meta)stable?

Sodium acetate is a common example used in general chemistry lectures to illustrate the idea of supersaturation, and that precipitation of a supersaturated solution can be initiated by a seed crystal. ...
6 votes
0 answers
135 views

Correct Definition of Absolute Electrode Potential

I thought absolute electrode potential is Galvani potential difference at the interface. However, it is given by following equation in John Bockris - Modern Electrochemistry (Ref.1): $$ E^M \mathrm{(...
6 votes
0 answers
775 views

How can copper(II) sulfate crystallize outside a glass vial?

I'm making copper sulfate crystals in glasses. Within a few weeks, the copper sulfate seems to crystallize both inside and outside the glass: (A few weeks after making a new solution) (Yet another ...
6 votes
0 answers
154 views

Dissolving ability of octane vs nonane on neoprene

I have been working with straight chain octane and nonane. The neoprene seals in some parts of the apparatus are allegedly far more vulnerable to the deleterious effects of octane than nonane - why? [...
6 votes
0 answers
1k views

How to dissolve a strong resin in difficult situation?

The resin is made up from two components: Component A: silicic acid, sodium salt (less than 10% sodium silicate) Component B: Diphenylmethane-4,4'-Diisocyanate, isomers and homologs (MDI,Polymer-MDI)...
5 votes
1 answer
78 views

How to remove glass shards out of a tiny hole to fit capillary tube?

This is oddly specific, but I am having trouble making the setup work for my electrochemical cell. We're doing Scanning Electrochemical Cell Microscopy (SECCM)* and the device has a capillary tube fit ...
5 votes
0 answers
123 views

Regarding the standard reduction potential and electrolyte/solid interface

I am modelling lithium-sulfur batteries ($\ce{LiS}$ batteries) and a strange phenomenom happens during charge, named infinite charging, which I show below: The factor $f_\mathrm{C}$ that appears in ...
5 votes
0 answers
232 views

Is there an alternative to potassium iodide as an electrolyte in dye-sensitized solar cells?

I'm helping my son build a dye-sensitized solar cell for his school project according to the directions on homemade-circuits.com. We're currently in the process of gathering the necessary materials. ...
5 votes
0 answers
99 views

Anomaly in Faraday's constant measurements

I was reading someone's biography, where the writer stated his early interest in Faraday's constant measurements (this is set six decades ago). My understanding was that Faraday constant is a true ...

15 30 50 per page
1
2 3 4 5
51