Unanswered Questions
389 questions with no upvoted or accepted answers
9
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1
answer
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Will the sulfur-iodine cycle and Haber Method work at lower pressures and temperatures?
I have a year-long research project next year in my senior year of high school, in which we have to make some product or prototype to solve some issue.
My interest was in the Liquid Fluoride ...
8
votes
0
answers
266
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Does water really have strong EM absorption at 3 kHz in solid and 2 GHz in liquid? Why the huge shift?
While writing this answer to the question Transmitter receiver coil separation for Electromagnetic Terrain Conductivity Measurement I ran across this large PDF file of a book Soil and Environmental ...
7
votes
0
answers
198
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How does the accumulation of hydrogen bonds affect individual bond strength?
I saw the question, "Is the strength of hydrogen bonding greater in hydrogen peroxide or water?" and it made me think of a question on hydrogen bonding:
If an oxygen on a water has a ...
7
votes
0
answers
667
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Dry water using graphite
Dry water or "powdered water" is essentially a bunch of extremely small water droplets surrounded by $\ce{SiO2}$.
Some time ago, I was messing around and mixed some powdered graphite with water. (The ...
6
votes
0
answers
164
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Why is supersaturated sodium acetate so (meta)stable?
Sodium acetate is a common example used in general chemistry lectures to illustrate the idea of supersaturation, and that precipitation of a supersaturated solution can be initiated by a seed crystal. ...
6
votes
0
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775
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How can copper(II) sulfate crystallize outside a glass vial?
I'm making copper sulfate crystals in glasses. Within a few weeks, the copper sulfate seems to crystallize both inside and outside the glass:
(A few weeks after making a new solution)
(Yet another ...
6
votes
0
answers
322
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Conductivity measurements of demineralized water - Unexpected results. Looking for explanation
I'm trying to measure the conductivity change of demineralized water over a few days. But I get results I can't explain.
Setup
This is the circuit and cell I'm using:
Where $R_x$ is the ...
6
votes
0
answers
2k
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How to dissolve slime jelly?
Suppose I have a small kid that had two cans of slime jelly (a Jelly made of water, glycerin, thickeners, dispersant, flavorings and pigments).
And that two cans were inside a backpack, and somehow ...
5
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0
answers
187
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What pH value of 1M sodium crotonate solution supposed to be?
I need to prepare the $\pu{1M}$ solution of sodium crotonate, however, I don't have one in lab, but I do have sodium hydroxide and crotonic acid.
Thus, I calculated that for $\pu{100 mL}$ of $\pu{1M}$ ...
5
votes
0
answers
237
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What acids, solvents is lithium-6 fluoride soluble in (other than HF)?
$\ce{LiF}$ is quite insoluble in water, and I'm trying to use some water-soluble acid or solvent to dissolve $\ce{^6LiF}$ (95% enriched) in. I'm not a chemistry person, I'm a radiation detection ...
5
votes
0
answers
793
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Solubility of PbSO4
The solubility of $\ce{PbSO4(s)}$ increase with the addition of $\ce{H2SO4}.$ Why?
I don't quite understand this. When dissolving $\ce{PbSO4(s)}$ we get the equilibrium equation:
$$\ce{PbSO4(s) <=...
5
votes
0
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479
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Why does pKw first decrease but eventually increase when temperature rises?
I understand the initial decrease in pKw.
$\ce{Heat + H2O (l) <=> H+ (aq) + OH- (aq)}$
Temperature increases, reaction shifts to the right, so
$\ce{H+} \text{ and } \ce{OH}$ ...
5
votes
0
answers
159
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Where is my antimony going?
I work in a trace metals laboratory operating an ICP-OES. I've been having some trouble with the recovery of antimony in a weak $\ce{HCl}$ solution post-digestion.
The antimony is part of a mix of ...
4
votes
1
answer
234
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How does a silver chloride electrode (Ag/AgCl) convert the potential in aqueous solution to the wire?
I am aware of the redox chemistry that happens at the electrode surface, but I'm not sure how exactly a change in electrical potential in the solution would change the potential in the electrode?
4
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86
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Notation for spectral density in experimental community
In an open quantum system setup where the system is coupled to infinite harmonic oscillators as bath (as in the Caldeira leggett model, for example), through the Hamiltonian,
$$H = \frac{\hat{p}^2}{2m}...