Unanswered Questions
375 questions with no upvoted or accepted answers
7
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answers
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How much CO2 is created during water electrolysis with a graphite anode?
I'm experimenting with water electrolysis and wanted to use non-toxic materials, so I settled on pure graphite rods for both electrodes and Epsom salt (magnesium sulfate) as the electrolyte. The ...
6
votes
0
answers
164
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Why is supersaturated sodium acetate so (meta)stable?
Sodium acetate is a common example used in general chemistry lectures to illustrate the idea of supersaturation, and that precipitation of a supersaturated solution can be initiated by a seed crystal. ...
6
votes
0
answers
775
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How can copper(II) sulfate crystallize outside a glass vial?
I'm making copper sulfate crystals in glasses. Within a few weeks, the copper sulfate seems to crystallize both inside and outside the glass:
(A few weeks after making a new solution)
(Yet another ...
5
votes
0
answers
187
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What pH value of 1M sodium crotonate solution supposed to be?
I need to prepare the $\pu{1M}$ solution of sodium crotonate, however, I don't have one in lab, but I do have sodium hydroxide and crotonic acid.
Thus, I calculated that for $\pu{100 mL}$ of $\pu{1M}$ ...
5
votes
0
answers
793
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Solubility of PbSO4
The solubility of $\ce{PbSO4(s)}$ increase with the addition of $\ce{H2SO4}.$ Why?
I don't quite understand this. When dissolving $\ce{PbSO4(s)}$ we get the equilibrium equation:
$$\ce{PbSO4(s) <=...
5
votes
0
answers
159
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Where is my antimony going?
I work in a trace metals laboratory operating an ICP-OES. I've been having some trouble with the recovery of antimony in a weak $\ce{HCl}$ solution post-digestion.
The antimony is part of a mix of ...
5
votes
0
answers
88
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Autocatalysis / Electroless plating of mercury
As a project I am trying to plate mercury onto a powdered metal amalgam of $\ce{Cu}$ & $\ce{Ag}$. I am using solution of $\ce{HgCl2}$ in normal $\ce{HCl}$ (a reducing agent), Any thoughts for ...
5
votes
0
answers
305
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Reduction of vanadyl ion
I want to reduce vanadyl to vanadium (III), can somebody please suggest some appropriate methods for it? I am trying to make a redox flow battery for a project but I have only vanadyl sulfate.
5
votes
1
answer
12k
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Electrolysis of concentrated sulphuric acid
In my textbook it is given that for electrolysis of dilute sulfuric acid at anode following reactions can occur:
At moderate concentrations
$\ce{2H2O -> O2 + H+ +4 e-}$
And for high ...
4
votes
1
answer
234
views
How does a silver chloride electrode (Ag/AgCl) convert the potential in aqueous solution to the wire?
I am aware of the redox chemistry that happens at the electrode surface, but I'm not sure how exactly a change in electrical potential in the solution would change the potential in the electrode?
4
votes
0
answers
86
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Notation for spectral density in experimental community
In an open quantum system setup where the system is coupled to infinite harmonic oscillators as bath (as in the Caldeira leggett model, for example), through the Hamiltonian,
$$H = \frac{\hat{p}^2}{2m}...
4
votes
1
answer
366
views
Variation of conductance of saturated aqueous solution with temperature
The following question was asked in JEE Mains 2020:
Let $C_{\ce{NaCl}}$ and $C_{\ce{BaSO4}}$ be the conductances (in S) measured for saturated aqueous solutions of $\ce{NaCl}$ and $\ce{BaSO4}$, ...
4
votes
0
answers
537
views
Electrolysis for rust removal: is "line of sight" a showstopper?
So I am using electrolysis to remove rust from a fuel tank. The tank is the cathode and a sacrificial anode is inserted where the fuel pump normally goes. It's not practical to put it anywhere else.
...
4
votes
0
answers
254
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Why does viscosity decrease when divalent cations are dissolved into aqueous solutions of sodium carboxymethylcellulose?
Sodium Carboxymethylcellulose (CMC/NaCMC/Aqualon) is a common product used in many instances for its unique properties, especially its ability to make solutions viscous. It is well known that the ...
4
votes
0
answers
1k
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An alternate purification process for sugar separation form bee honey?
Bee honey contains 75% sugars (Fructose, Glucose, Maltose, Sucrose and others), some water and low amount of different compounds (up to 5%) Wiki.
Basic purification is done by addition of phosphoric ...