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2 votes
2 answers
85 views

White powder-like substance on top of sodium hydroxide solution

i've made sodium hydroxide solution adding 100g of hydroxide to water 100g. i've been adding it slowly and constantly stirring. few days later on top of solution was thick layer of white powder. it ...
-2 votes
1 answer
79 views

Can ZrO2 be made fluoride resistant?

$\ce{ZrO2}$ has great properties, biocompatibility, chemical resistance, decent scratch resistance, great thermal resistance and refraction, but it could be better. It, like glass, will slowly react ...
11 votes
2 answers
307 views

Silver Tarnish and Reactivity Series

I read that silver in the presence of hydrogen sulfide corrodes to form silver sulfide and hydrogen. $$\ce{Ag + H2S -> Ag2S + H2}$$ But in the reactivity series silver is placed much below hydrogen....
-2 votes
1 answer
46 views

Why mono and dioxides of germanium,tin and lead are amphoteric

I get that group 14 elements show +4 and +2 oxidation states so they can form both ionic and covalent compounds and so they are amphoteric but monoxide means that these elements have to show +2 ...
3 votes
0 answers
99 views

Does solid manganese reacts with atmospheric air when heated?

As discussed in my answer, manganese is not particularly reactive to air. The surface of manganese lumps oxidize to a minor extent but when it is finely divided, it becomes pyrophoric and burns in air....
9 votes
2 answers
480 views

I can't choose the set of 3 chemicals with each of which Si will react (out of 5 possible sets)

This is one of the questions used in the Russian State Chemistry Exam. One needs to select the set of chemicals in the second column such that each of them would react with the element or chemical in ...
4 votes
3 answers
1k views

Does manganese reacts with water at "not" standard conditions?

In my answer, I stated that manganese is said to not react with water under normal conditions although some sources say it reacts with water to liberate hydrogen gas. Does it implies that it reacts ...
6 votes
2 answers
4k views

What noble metal is most resistant to oxidation by diatomic oxygen in air at room and elevated temperatures?

To clarify, by noble metals in this case I mean all platinum metals + gold, no copper, silver or rhenium. These noble metals are described as having low reactivity, but which one is least reactive or ...
1 vote
1 answer
3k views

Here are four observations of the reactions of four metals

Here are four observations of the reactions of four metals. Metal F and G react slowly with water Metal H displaces metal G from its chloride salt solution Metal E does not react with dilute acids ...
10 votes
3 answers
60k views

How can I relate the reactivity series to electronegativity and ionization energy?

I am trying to figure out how the reactivity series comes about. My understanding is that elements with a higher electronegativity will be more reactive than elements with a lower electronegativity, ...
2 votes
0 answers
189 views

Why doesn't XeF6 displace oxygen from water?

Consider the following reactions (unbalanced): $$ \begin{align} \ce{XeF2 + H2O &→ Xe + HF + O2} \tag{a} \\ \ce{XeF4 + H2O &→ XeO3 + Xe + O2 + HF} \tag{b} \\ \ce{XeF6 + H2O &→ XeO3 + HF} \...
10 votes
3 answers
65k views

Why doesn't copper react with hydrochloric acid while the other metals do?

5) Which one of the following metals does not react with hydrochloric acid? A. zinc B. magnesium C. iron D. copper E. aluminium The right answer must be copper, but why ...
5 votes
1 answer
2k views

p-Nitroaniline reaction with sulfuric acid

An alternative version of the well-known demonstration carbon snake (the dehydration reaction of sugar by concentrated sulfuric acid forming a column of graphite) consists in mixing paranitroaniline ...
11 votes
1 answer
465 views

Why does radium form a nitride rather than oxide when exposed to air?

The Wikipedia article states: Pure radium is silvery-white, but it readily reacts with nitrogen (rather than oxygen) on exposure to air, forming a black surface layer of radium nitride ($\ce{Ra3N2}$)....
2 votes
1 answer
224 views

Why is it technically inaccurate to say that the decrease in reactivity of halogens is due to decreasing electronegativity?

I came across the following information in this post. Below the infographic there is a paragraph with a disclaimer: As another disclaimer, the reactivity of the halogens decreasing down the group ...

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