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Questions tagged [optical-properties]

Questions related to color as well as the reflecting and refracting properties of chemicals.

5 votes
1 answer
195 views

Optical techniques for kinetics studies

What optical methods can be used to measure the concentration of reacting gases in a reactor during an exothermic and fast reaction? I need to monitor and measure the local concentration of my gases (...
16 votes
1 answer
2k views

What is happening in this video of solvated electrons donated from sodium in ammonia?

I just saw the Periodic Video Liquid Electrons - Periodic Table of Videos where sodium is added to liquid ammonia. The demonstration shows that even if electrons are solvated, if you have a high ...
6 votes
1 answer
358 views

How do I run MP2 and/or CCSD-level hyperpolarizability calculations with GAMESS?

I have used GAMESS before for TDHF (RPA) / TDDFT level first hyperpolarizability ($\beta$) calculations. However, I cannot figure out how to calculate $\beta$ with MP2 and CCSD for comparative ...
1 vote
1 answer
973 views

How do chemical bonds increase molecular refractivity?

I see that the molecular refractivity of a compound consists of the refractivity indexes of its composite atoms and chemical bonds, and that the refractive index $n$ of a substance increases with its ...
1 vote
2 answers
198 views

Permanent cloudy colloid with water

I need to make a cloudy white liquid where the particles won't eventually settle out. It will be exhibiting the Tyndall effect for a very long time. I'd use milk, but I don't want it to become rancid....
36 votes
3 answers
7k views

A compound that absorbs all visible light

Is there a compound that absorbs all visible light?
6 votes
1 answer
497 views

D-Threose: reduction and optical activity

I've bumped into this exercise: Judging by the mechanism of reaction between D-threose and $\ce{NaBH4}$, do you think the final product will be optically active? To me looks like a reduction, ...
2 votes
1 answer
104 views

Finding a substance which has a continuous gradient in refractive index

I need to find a substance whose refractive index is constantly changing and directly proportional to the square root of the depth. I know I'm looking for a lot, but I'd really appreciate any ideas or ...
6 votes
2 answers
8k views

UV-Transparent Plastic?

I am looking for a type of plastic, preferably in the form of a sheet or film, that is weatherproof, durable, flexible, and both transparent and UV-transparent. Most films I've seen so far are treated ...
8 votes
1 answer
508 views

Discovery of optical activity of enantiomers - where did the idea of using polarized light came from?

According to Wikipedia, optical activity was first observed in 1811 in quartz. Louis Pasteur's contribution is also mentioned there and in other sources as a major advancement in establishing optical ...
5 votes
0 answers
47 views

Is there any molecule describable by three-level with mixed parity and transition dipole moments in different directions?

I would like to know if there are molecules described by a three-level system with mixed parity and transition dipole moments in different directions. By mixed parity I mean all three transitions can ...
1 vote
3 answers
263 views

Simple enantiomer in powder form?

I want to do some experiments on enantiomers. As it involves some calculations of potential energy surfaces, I would like to do this experiment on a simple enantiomer (For example $\ce{CHBrClF}$). But ...
6 votes
1 answer
6k views

Why does zinc sulfide glow?

Zinc sulfide is used in road signs because when light from cars hit the road signs, it glows. What actually is the reason for the glowing of road signs (actually glowing of $\ce{ZnS}$)?
4 votes
0 answers
52 views

Is optical activity of a given compound a statistical picture?

When optical activity is taught it is done in terms of single molecules. But when it is actually measured it is done on a large collection of such molecules. So, how does the asymmetry manifest itself ...
2 votes
1 answer
338 views

Suggestions for 200-600 nm range transmitting polymers/materials

I am a student of physics who is doing research related to Cherenkov measurements. For that purpose, I need suggestions for some materials that have the following properties: $80\%$ transparency in ...

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