Questions tagged [optical-properties]
Questions related to color as well as the reflecting and refracting properties of chemicals.
160
questions
5
votes
1
answer
195
views
Optical techniques for kinetics studies
What optical methods can be used to measure the concentration of reacting gases in a reactor during an exothermic and fast reaction? I need to monitor and measure the local concentration of my gases (...
16
votes
1
answer
2k
views
What is happening in this video of solvated electrons donated from sodium in ammonia?
I just saw the Periodic Video Liquid Electrons - Periodic Table of Videos where sodium is added to liquid ammonia. The demonstration shows that even if electrons are solvated, if you have a high ...
6
votes
1
answer
358
views
How do I run MP2 and/or CCSD-level hyperpolarizability calculations with GAMESS?
I have used GAMESS before for TDHF (RPA) / TDDFT level first hyperpolarizability ($\beta$) calculations. However, I cannot figure out how to calculate $\beta$ with MP2 and CCSD for comparative ...
1
vote
1
answer
973
views
How do chemical bonds increase molecular refractivity?
I see that the molecular refractivity of a compound consists of the refractivity indexes of its composite atoms and chemical bonds, and that the refractive index $n$ of a substance increases with its ...
1
vote
2
answers
198
views
Permanent cloudy colloid with water
I need to make a cloudy white liquid where the particles won't eventually settle out. It will be exhibiting the Tyndall effect for a very long time.
I'd use milk, but I don't want it to become rancid....
36
votes
3
answers
7k
views
A compound that absorbs all visible light
Is there a compound that absorbs all visible light?
6
votes
1
answer
497
views
D-Threose: reduction and optical activity
I've bumped into this exercise:
Judging by the mechanism of reaction between D-threose and $\ce{NaBH4}$, do you think the final product will be optically active?
To me looks like a reduction, ...
2
votes
1
answer
104
views
Finding a substance which has a continuous gradient in refractive index
I need to find a substance whose refractive index is constantly changing and directly proportional to the square root of the depth. I know I'm looking for a lot, but I'd really appreciate any ideas or ...
6
votes
2
answers
8k
views
UV-Transparent Plastic?
I am looking for a type of plastic, preferably in the form of a sheet or film, that is weatherproof, durable, flexible, and both transparent and UV-transparent. Most films I've seen so far are treated ...
8
votes
1
answer
508
views
Discovery of optical activity of enantiomers - where did the idea of using polarized light came from?
According to Wikipedia, optical activity was first observed in 1811 in quartz. Louis Pasteur's contribution is also mentioned there and in other sources as a major advancement in establishing optical ...
5
votes
0
answers
47
views
Is there any molecule describable by three-level with mixed parity and transition dipole moments in different directions?
I would like to know if there are molecules described by a three-level system with mixed parity and transition dipole moments in different directions. By mixed parity I mean all three transitions can ...
1
vote
3
answers
263
views
Simple enantiomer in powder form?
I want to do some experiments on enantiomers. As it involves some calculations of potential energy surfaces, I would like to do this experiment on a simple enantiomer (For example $\ce{CHBrClF}$). But ...
6
votes
1
answer
6k
views
Why does zinc sulfide glow?
Zinc sulfide is used in road signs because when light from cars hit the road signs, it glows. What actually is the reason for the glowing of road signs (actually glowing of $\ce{ZnS}$)?
4
votes
0
answers
52
views
Is optical activity of a given compound a statistical picture?
When optical activity is taught it is done in terms of single molecules. But when it is actually measured it is done on a large collection of such molecules. So, how does the asymmetry manifest itself ...
2
votes
1
answer
338
views
Suggestions for 200-600 nm range transmitting polymers/materials
I am a student of physics who is doing research related to Cherenkov measurements. For that purpose, I need suggestions for some materials that have the following properties:
$80\%$ transparency in ...