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8 questions with no upvoted or accepted answers
5 votes
0 answers
479 views

Why does pKw first decrease but eventually increase when temperature rises?

I understand the initial decrease in pKw. $\ce{Heat + H2O (l) <=> H+ (aq) + OH- (aq)}$ Temperature increases, reaction shifts to the right, so $\ce{H+} \text{ and } \ce{OH}$ ...
K-Feldspar's user avatar
  • 2,853
2 votes
0 answers
43 views

Analytically combining Dynamic Equilibria that have a two way affect?

Lets say I want to model a water system as the following set of equilibria: $\ce{H2O <=> OH- + H3O+}$ | $\ce{A=[OH^{-}][H3O+]}$ $\ce{CO2 + H2O <=> H2CO3}$ | $\ce{B=\frac{[H2CO3]}{[CO2]}}$...
J-S's user avatar
  • 939
1 vote
0 answers
100 views

Is it a coincidence that pKw = 14.00 at SATP?

High school chemistry student here. For our purposes in class for studying acids and bases, we are taught that $\text{p}K_\text{w}=14.00$, which is central for many of our calculations. I assume this ...
986's user avatar
  • 207
1 vote
0 answers
1k views

Can water be included in an ICE table if it is not the solvent and is a product?

The question that I have is whether you will count water in a Fischer esterification equilibrium problem where the equation is carboxylic acid + ethanol --> ethyl acetate + Water We need to find the ...
sarah o's user avatar
  • 11
1 vote
0 answers
830 views

Selectivity Coefficients of Ion Exchange Resins - Selectivity Reversal with TDS / Ionic Strength

I'm currently studying ion exchange resins and generally getting a bit stuck on some points of information which I do not fully understand / are not very well explained within the literature. I ...
user1257's user avatar
0 votes
0 answers
51 views

Which reaction is happening in the preparation of sulfuric acid through contact process?

I've read that in the preparation of $\ce{H2SO4}$ through the Contact process, on the absortion tower, the gas $\ce{SO3}$ is getting in contact with $\ce{H2SO4} (l)$ , because adding $\ce{SO3}$ to $\...
user117647's user avatar
0 votes
0 answers
60 views

Can I freeze water at 100 °C if I add 28 grams NaCl in 100 grams water?

Can I freeze water at 100 °C if I add 28 grams NaCl in 100 grams water at 20 °C? I found this diagram that says, if I have 28.05 wt% NaCl in water, then the equilibrium temperature between two phases ...
sotirios's user avatar
0 votes
0 answers
176 views

How the heat a large amount of water that is safe to use?

I would like to know how heat up a large amount of water ( assumption : 100 liter ) that people could use to take their bath and also it would not be dangerous even if they accidentally ingested it ? ....
syirazi siraj's user avatar