All Questions
Tagged with equilibrium analytical-chemistry
26
questions
-1
votes
2
answers
2k
views
Equilibrium constant for esterification process
Teacher told us that the concentration term for pure liquids and solids is always $1$. But online I found this reaction:
$$\ce{CH3COOH(l) + CH3CH2OH(l) <=> CH3COOCH2CH3(l) + H2O(l)}$$
...
- 41
6
votes
1
answer
111
views
Distribution coeffecient without concentrations
From what I understand about distribution coefficient is straight from my book — which does not give any practice examples — is that
$$D = \frac{C_\mathrm{A}(\text{ext})}{C_\mathrm{A}(\text{orig})}$$ ...
- 71
1
vote
2
answers
2k
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Calculating solubility of iron(III) hydroxide in water
The following example in Skoog's Analytical Chemistry uses mass-balance and charge-balance equations to calculate the solubility of iron(III) hydroxide in aqueous solution.
$$
\begin{align}
\ce{Fe(...
- 811
0
votes
1
answer
71
views
Volume of NaOH needed to precipitate copper(II) but not calcium
I have $\ce{NaOH}: C = \pu{0.1M}, V_{\ce{NaOH}}$ that I want to progressively add in a solution (in water) of:
$$\begin{align}
\ce{Cu^{2+}}&: \pu{0.01M}; & K_\mathrm{sp} &= 10^{-18.6} \\
\...
- 121
1
vote
2
answers
1k
views
Kc(equilibrium constant) and Kp
Its given in the book that at 12.18kelvin Kc=Kp. How is that equated from the equation Kp= Kc(RT)^∆ng. I am unable to sort it out, please guide me in to the topic....
- 183
3
votes
0
answers
331
views
The behaviour of Ag3PO4 in solution
To a $\pu{1L}$ flask, we add $\pu{4.1900 g}$ ($\pu{0.01001 mol}$) of $\ce{Ag3PO4}$, then fill it up with water. Knowing the following constants, we are asked to find the concentration of all species ...
- 587
2
votes
0
answers
547
views
Apparent solubility of Ag2C2O4 in a buffer solution
We take the following quantities and mix them together:
$\pu{20 mL}$ solution of $\ce{AgNO3}$ $\pu{0.001 mol//dm3}$
$\pu{20 mL}$ solution of $\ce{H2C2O4}$ $\pu{0.200 mol//dm3}$
$\pu{40 mL}...
- 587
2
votes
0
answers
143
views
How to calculate concentrations when dissolving two salts?
Some solid silver bromate was dissolved together with solid silver acetate what would be the highest achievable pH?
\begin{align}
K_\mathrm{sp}(\ce{AgBrO3}) &= 5.38 \times 10^{-5}\\
K_\mathrm{sp}...
- 7,402
9
votes
2
answers
8k
views
Short Cut Method to Calculating pH of Polyprotic Acid?
I am doing the following question:
Calculate the pH of a $4.00\ \mathrm{mol\ L^{-1}}$ solution of citric acid.
$\mathrm{pK_{a1}} = 3.09~~~~~ \mathrm{pK_{a2}} = 4.75~~~~~ \mathrm{pK_{a3}} = 6.40$
...
- 7,402
6
votes
1
answer
7k
views
Difference in calculated pH and the real pH of a phosphate buffer
I want to prepare a buffer system with $\mathrm{pH} = 7.00$ and a total concentration $c_\mathrm{tot} = \pu{0.10 mol l^-1}$ using sodium hydrogen phosphate $(\ce{Na2HPO4})$ and sodium dihydrogen ...
- 71
1
vote
1
answer
437
views
Analytical Chemistry Textbook Recommendation [duplicate]
Could anyone recommend a good book for self-learning that provide a clear, step by step guide on solving such chemical equilibria questions.
It should cover the following topics: weak acid and ...
- 7,402