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9 votes
2 answers
8k views

Short Cut Method to Calculating pH of Polyprotic Acid?

I am doing the following question: Calculate the pH of a $4.00\ \mathrm{mol\ L^{-1}}$ solution of citric acid. $\mathrm{pK_{a1}} = 3.09~~~~~ \mathrm{pK_{a2}} = 4.75~~~~~ \mathrm{pK_{a3}} = 6.40$ ...
Nanoputian's user avatar
  • 7,402
6 votes
1 answer
7k views

Difference in calculated pH and the real pH of a phosphate buffer

I want to prepare a buffer system with $\mathrm{pH} = 7.00$ and a total concentration $c_\mathrm{tot} = \pu{0.10 mol l^-1}$ using sodium hydrogen phosphate $(\ce{Na2HPO4})$ and sodium dihydrogen ...
camibuidi's user avatar