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57 votes
4 answers
385k views

Why is it important to use a salt bridge in a voltaic cell? Can a wire be used?

I was learning about voltaic cells and came across salt bridges. If the purpose of the salt bridge is only to move electrons from an electrolyte solution to the other, then why can I not use a wire? ...
Peeyush Kushwaha's user avatar
22 votes
3 answers
2k views

True or false: "A used AA battery contains fewer moles of electrons than a new AA battery."

I recently took a Gen. Chem. 2 exam that contained this question. I answered false, but my professor said the answer is true. My reasoning was that any electrons that leave the anode end up at the ...
Logicus's user avatar
  • 449
15 votes
7 answers
111k views

Which is anode and which is cathode?

A maybe (hopefully) simple question about the denotations of "anode" and "cathode". The below image is a schematic of a polymer solar cell (Source (WBM)). (The figure text is quoted as well for the ...
Steeven's user avatar
  • 930
10 votes
3 answers
13k views

Why is chloride oxidised instead of water in copper chloride electrolysis?

For the Electrolysis of Copper Chloride: Cathode: $\ce{Cu^{2+} + 2e- <=> Cu}$ Anode: $\ce{2Cl <=> Cl2 + 2e- }$ I am confused about the reaction taking place at the anode. Wouldn't $\ce{...
Luke Taylor's user avatar
8 votes
0 answers
392 views

What exactly is an "electron-sponge"?

What exactly an "electron-sponge" [behavior/action/property/system] nickname is, and what makes a material an "electron-sponge" (preferably, quantitatively)? From what I found, it's typically a ...
andselisk's user avatar
  • 38.4k
7 votes
2 answers
4k views

What are high-energy electrons?

I read that (in cellular respiration) the transported electrons in NADH have a higher energy than those in FADH2. I can't find a (simple or otherwise) explanation of what a "high-energy" ...
Naj's user avatar
  • 267
7 votes
1 answer
392 views

Prediction of ionic reduction?

Here are some standard electrode potentials:- $$\ce{SO_4^{2-} + 4H^+ + 2e^- -> SO_2 + 2H_2O}\\E^o=0.17\mathrm{V}\\ \ce{NO_3^- + 4H^+ + 3e^- -> NO + 2H_2O}\\E^o=0.97\mathrm{V}\\ \ce{NO_3^- + ...
stochastic13's user avatar
  • 6,795
5 votes
2 answers
22k views

Explanation for the reactions in a saltwater battery with zinc and copper electrodes

I am a physicist, not a chemist. I'm trying to get a basic understanding of the reactions taking place in a battery using a saltwater electrolyte with copper and zinc terminals. I'm writing a general ...
abalter's user avatar
  • 151
5 votes
1 answer
6k views

Current in a galvanic cell

I was looking through chemistry textbooks to find out how to determine how much current a galvanic cell should generate and what affects that current value. However, I did not find anything: textbooks ...
user510's user avatar
  • 864
5 votes
1 answer
3k views

In a galvanic cell where the two electrodes are in the same electrolyte solution, why do reduction and oxidation occur separately?

In a certain book, I was presented with the following solution: An iron nail is attached by a piece of wire to a magnesium ribbon, and the iron and magnesium are placed into the same container, with ...
user29677's user avatar
4 votes
2 answers
5k views

Why Fe 3+ is more common than Fe 2+

I heard that $\ce{Fe}(\mathrm{III})$ is more common than $\ce{Fe}(\mathrm{II})$ but I've not heard a very clear explanation. Could someone please explain this incorporating electron configurations in ...
Crystal Optics's user avatar
3 votes
1 answer
2k views

Electrode potentials at interfaces?

My questions relates to the fundamental concept of electrochemistry, more specifically the electrode potentials. 1) First, why is there a potential difference at the interface of two phases? ...
stochastic13's user avatar
  • 6,795
3 votes
1 answer
356 views

Balancing redox equation

So I had these two reactions that confused me .. I tried the standard way of balancing it (Putting oxygen number everywhere, +1,+2,-2 etc.) and then go on with it but it didn't work So anyways here ...
cene's user avatar
  • 31
3 votes
1 answer
189 views

Are my intuitions about how batteries work right? [closed]

Being really fascinated by how electricity actually works, I started studying batteries. I initilally understimated the complexity of this apparently-simple objects, and thorugh studies and researches ...
Gabriele Scarlatti's user avatar
2 votes
1 answer
2k views

Why can't electrons be transferred using hydrogen ions?

Recognizing how oxidation and reduction occurs is essential for analyzing and understanding biochemical reactions. Which of the following methods would NOT be employed in transferring electrons in ...
trav95's user avatar
  • 443

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