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57 votes
4 answers
385k views

Why is it important to use a salt bridge in a voltaic cell? Can a wire be used?

I was learning about voltaic cells and came across salt bridges. If the purpose of the salt bridge is only to move electrons from an electrolyte solution to the other, then why can I not use a wire? ...
Peeyush Kushwaha's user avatar
37 votes
5 answers
20k views

Why don't the electrons move through the electrolyte (instead of the circuit) in a galvanic cell?

I was learning about galvanic cells and I had a problem understanding why electrons do not travel through the electrolyte solutions themselves, instead preferring to travel through metals. Can ...
Xman's user avatar
  • 483
12 votes
6 answers
592 views

Is there any electronic component to water conductivity?

Answers to Decrease in temperature of a aqueous salt solution decreases conductivity indicate that the electrical conductivity of salt solutions arises from the mobility of ionic species and therefore ...
uhoh's user avatar
  • 5,900
10 votes
3 answers
13k views

Why is chloride oxidised instead of water in copper chloride electrolysis?

For the Electrolysis of Copper Chloride: Cathode: $\ce{Cu^{2+} + 2e- <=> Cu}$ Anode: $\ce{2Cl <=> Cl2 + 2e- }$ I am confused about the reaction taking place at the anode. Wouldn't $\ce{...
Luke Taylor's user avatar
5 votes
2 answers
22k views

Explanation for the reactions in a saltwater battery with zinc and copper electrodes

I am a physicist, not a chemist. I'm trying to get a basic understanding of the reactions taking place in a battery using a saltwater electrolyte with copper and zinc terminals. I'm writing a general ...
abalter's user avatar
  • 151
15 votes
7 answers
111k views

Which is anode and which is cathode?

A maybe (hopefully) simple question about the denotations of "anode" and "cathode". The below image is a schematic of a polymer solar cell (Source (WBM)). (The figure text is quoted as well for the ...
Steeven's user avatar
  • 930
9 votes
1 answer
283 views

Fundamentals of Li-ion Functionality

I would like to have an in-depth understanding of Li-ion batteries functionality, at atomic level. Can anyone help me to understand it? I have included some known background to support my questions. ...
Physther's user avatar
  • 944
3 votes
1 answer
2k views

Electrode potentials at interfaces?

My questions relates to the fundamental concept of electrochemistry, more specifically the electrode potentials. 1) First, why is there a potential difference at the interface of two phases? ...
stochastic13's user avatar
  • 6,795
2 votes
2 answers
2k views

Why does copper form bubbles in vinegar in this situation?

I watched this video in which the host tries to show the principles behind the voltaic pile. The host first immersed zinc in vinegar and bubbles are observed forming around zinc. I've learned that ...
Gabriele Scarlatti's user avatar