All Questions
Tagged with electrons electrochemistry
76
questions
-3
votes
1
answer
79
views
Does the cathode always attain a positive charge or is it just a convention?
Suppose I have a galvanic cell composed of two half cells, one containing Zinc electrode dipped in an electrolytic solution (say of ZnSO4) while the another one having Lithium electrode dipped in ...
5
votes
1
answer
81
views
Correct Interpretation of Apparent Charge Transfer Coefficients
Good day guys,
I was looking over some $i$ vs $\eta $ for a redox reaction over a copper cathode, the cell has $\ce{LiBf4}$ in THF as the electrolyte. The main reaction taking place is:
$$\ce{N2 + 6 ...
0
votes
0
answers
24
views
Degradation via electrolysis and electrode surface area
What is the relationship between electrode surface area and processes such as electrolysis/electrode polarization?
Let's say for example I want a fixed electric field between two electrodes in a ...
0
votes
2
answers
85
views
Fundamental understanding of electrode potentials
The electrical double layer, is commonly used to describe the origins of electric potentials that is fundamental to electrochemistry. This model is quite outdated from my understanding, but it is ...
13
votes
3
answers
2k
views
Do electrons really hang around the electrode while ions go take a swim?
This answer to this post addresses "what happens if you dip a single zinc electrode into some electrolyte solution." It explains that
However, though the zinc ion can diffuse through the ...
0
votes
2
answers
39
views
Electrolysis to refine metals
Why does the cathode get bigger and the anode smaller when we use copper electrodes for the electrolysis of Copper Sulphate? Why does the anode not receive electrons from the anions (e.g Sulphate and ...
-3
votes
1
answer
68
views
Aqueous electrons in electrochemical cells [closed]
In the context of a zinc-copper electrochemical cell, zinc atoms at the anode are oxidized, releasing electrons and forming zinc ions that dissolve into the solution ($\ce{Zn(s) -> Zn^{2+}(aq) + 2e-...
2
votes
1
answer
96
views
Do solvated electrons short circuit the electrolysis of liquid ammonia
If attempting the electrolysis of liquid ammonia using NaNH2 as an electrolyte. It is understood that Na+ will form solvated electrons. I understand that these solvated electrons can dramatically ...
-2
votes
2
answers
123
views
How do electrons travel through a fuel cell or flow battery with multiple cells?
I understand that if you have a fuel cell or flow battery with a single cell that electrons will go from the electrode and through an external circuit across the load which the fuel cell / flow ...
21
votes
2
answers
644
views
Some materials emit more photoelectrons than others - why?
I've been experimenting with some materials by changing the wavelength of the incident light on the material and detecting photoelectrons, like in the diagram below:
I might get a response that looks ...
3
votes
1
answer
2k
views
Electrode potentials at interfaces?
My questions relates to the fundamental concept of electrochemistry, more specifically the electrode potentials.
1) First, why is there a potential difference at the interface of two phases? ...
12
votes
6
answers
592
views
Is there any electronic component to water conductivity?
Answers to Decrease in temperature of a aqueous salt solution decreases conductivity indicate that the electrical conductivity of salt solutions arises from the mobility of ionic species and therefore ...
-3
votes
1
answer
254
views
What is the purpose of the solution in a galvanic cell?
In other words: What is the purpose of the solution that the electrodes are immersed in, in a galvanic cell, and is it possible to generate a current without any solution?
2
votes
1
answer
3k
views
Trends in conductivity in groups 1 and 2
I have read that the trend for conductivity in groups 1 and 2 is a decrease down the groups (generally). Apparently this is because the atoms of each element get larger, so while the number of ...
-5
votes
1
answer
90
views
Is the given figure correct? Does the electron really flow out as depicted by the arrow? [closed]
Someone up here questioned about the figure and that the arrow is pointless and doesnt make sense? Or is it?