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-3 votes
1 answer
254 views

What is the purpose of the solution in a galvanic cell?

In other words: What is the purpose of the solution that the electrodes are immersed in, in a galvanic cell, and is it possible to generate a current without any solution?
Special K's user avatar
5 votes
2 answers
784 views

Formation of species in electrolysis

I understand the principles of electrolysis of salts in aqueous solutions, but there are two points on which i am unsure. At the positive electrode, how can you work out which ions will ...
ziggy's user avatar
  • 726
2 votes
1 answer
2k views

The anode and cathode when corrosion happens

Let's say $\ce{Fe}$ reacts with $\ce{Cu^{2+}}$ ions. $\ce{Fe}$ would oxidize and therefore give electrons to $\ce{Cu^{2+}}$so that: $$\ce{Fe-> Fe^{2+} +2e-}$$ $$\ce{Cu^{2+} +2e^- ->Cu}$$ The ...
didnotcomeuptosomething's user avatar
4 votes
1 answer
998 views

Reduce chlorine gas

I have a simple electrolysis setup which uses aqueous sodium chloride as electrolyte. The problem is that, the setup makes tons of chlorine gas along with hydrogen (I only want hydrogen). I didn't ...
AvZ's user avatar
  • 563
10 votes
3 answers
13k views

Why is chloride oxidised instead of water in copper chloride electrolysis?

For the Electrolysis of Copper Chloride: Cathode: $\ce{Cu^{2+} + 2e- <=> Cu}$ Anode: $\ce{2Cl <=> Cl2 + 2e- }$ I am confused about the reaction taking place at the anode. Wouldn't $\ce{...
Luke Taylor's user avatar
5 votes
2 answers
22k views

Explanation for the reactions in a saltwater battery with zinc and copper electrodes

I am a physicist, not a chemist. I'm trying to get a basic understanding of the reactions taking place in a battery using a saltwater electrolyte with copper and zinc terminals. I'm writing a general ...
abalter's user avatar
  • 151
3 votes
1 answer
109 views

Since aqueous acids release Hydrogen cations into the solution, will an electric current create Hydrogen gas?

I was wondering that since acids dissociate in water to make a lot of $\ce{H+}$ cations. Is it possible that introducing a supply of electrons via an electric current, would create $\ce{H2}$ gas?
Klik's user avatar
  • 720
1 vote
2 answers
481 views

What's the voltage of a battery?

The definition of voltage I'm familiar with is the amount of electric potential energy per unit charge at a location. My prof defined the voltage of a battery to be the amount of potential energy ...
dfg's user avatar
  • 151
3 votes
1 answer
192 views

Intuition for electrode potential

If I connect a zinc half cell (Left hand side) and a copper half cell (right hand side), I get an E cell value of 1.1V taken from the voltmeter. If I replace the voltmeter with a light bulb, I will ...
Eliza's user avatar
  • 2,423
7 votes
1 answer
392 views

Prediction of ionic reduction?

Here are some standard electrode potentials:- $$\ce{SO_4^{2-} + 4H^+ + 2e^- -> SO_2 + 2H_2O}\\E^o=0.17\mathrm{V}\\ \ce{NO_3^- + 4H^+ + 3e^- -> NO + 2H_2O}\\E^o=0.97\mathrm{V}\\ \ce{NO_3^- + ...
stochastic13's user avatar
  • 6,795
3 votes
1 answer
2k views

Electrode potentials at interfaces?

My questions relates to the fundamental concept of electrochemistry, more specifically the electrode potentials. 1) First, why is there a potential difference at the interface of two phases? ...
stochastic13's user avatar
  • 6,795
57 votes
4 answers
385k views

Why is it important to use a salt bridge in a voltaic cell? Can a wire be used?

I was learning about voltaic cells and came across salt bridges. If the purpose of the salt bridge is only to move electrons from an electrolyte solution to the other, then why can I not use a wire? ...
Peeyush Kushwaha's user avatar
3 votes
1 answer
554 views

Why does electrolysis take so much time?

What makes electrolysis or electroplating take so long ? What stage takes longer when ions are attracted to electrodes or when they gain or lose electrons at electrode. And if we are talking about an ...
Abdelrahman Esmat's user avatar
37 votes
5 answers
20k views

Why don't the electrons move through the electrolyte (instead of the circuit) in a galvanic cell?

I was learning about galvanic cells and I had a problem understanding why electrons do not travel through the electrolyte solutions themselves, instead preferring to travel through metals. Can ...
Xman's user avatar
  • 483
3 votes
1 answer
1k views

Extraction of hydrogen and oxygen from water

The apparatus that I am using is a glass container, with two electrodes,two glass cylinders, water, and a battery. In the glass container will be filled with water and two electrodes kept inside the ...
Siddharth Warrier's user avatar

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