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2 votes
1 answer
67 views

Does solubility product dictate predominant precipitate from the solution with several ionic compounds?

While removing temporary hardness through boiling, magnesium bicarbonate will give $\ce{Mg(OH)2}.$ $\ce{Mg(OH)2}$ predominates over $\ce{MgCO3}$ as the solubility product $K_\mathrm{sp}$ of $\ce{Mg(OH)...
Avaneesh B's user avatar
1 vote
0 answers
375 views

Who is more polar: acetonitrile or methanol?

According to data dipole moment of acetonitrile is around 4 while that of methanol is 1.7 but is said that acetonitrile is more soluble in non polar solvent that methanol. But shouldn't methanol be ...
Curious's user avatar
  • 21
2 votes
2 answers
145 views

In an unsaturated solution, is the product of ions still equal to Ksp?

Suppose I have a solution of a sparingly soluble compound, and consider its solubility in g/L. If I have less g/L of solution than that amount, it means the solution is unsaturated, but what happens ...
odin98's user avatar
  • 67
-1 votes
1 answer
44 views

Solubility of hydrogen

I'm interested in bacterial fermentation which produces molecular hydrogen as an end product. If bacteria produce molecular hydrogen in solution under anaerobic conditions, does this remain dissolved ...
JadeD's user avatar
  • 7
1 vote
0 answers
75 views

What does it mean for a substance to be "sparingly soluble"?

I have trouble understanding what solubility means. Merriam-Webster defines it as follows: 1 the quality or state of being soluble 2 the amount of a substance that will dissolve in a given amount of ...
odin98's user avatar
  • 67
-2 votes
1 answer
118 views

Small (personal) scale sea salt production?

I was looking to try to make a small setup for producing small amounts of sea salt. Ideally a series of evaporation chambers, with a heavy brine as the finished product, that could then be baked. May ...
user139996's user avatar
1 vote
1 answer
157 views

Solubility of SrF2 in aqueous solution of NaF

This might be really simple question but I have no idea how to proceed to solve such kind of question. The solubility product of $\ce{SrF2}$ in water is $\pu{8E-10}$. Calculate its solubility in 0.1M ...
izack's user avatar
  • 23
2 votes
1 answer
103 views

Equilibrium Solubility of CO2 in Aqueous Solution and its Dependence on H3O+ Concentration

The equilibrium solubility of $\ce{CO2}$ in an aqueous solution is given by three chemical reactions: $$ \begin{align} \ce{CO2(g) &<=> CO2(aq)}\label{rxn:R1}\tag{R1}\\ \ce{CO2(aq) + H2O &...
Lineare Libelle's user avatar
2 votes
1 answer
86 views

Are all salts completely dissociated in solution when put in smaller amounts than their molar solubility?

From what I understand, the solubility is given in terms of molar solubility (or $\pu{K_{sp}}$), from which it can be easily calculated). Indeed, the saturation point represents the maximum amount of ...
odin98's user avatar
  • 67
1 vote
1 answer
117 views

Scrubbing methanol and ethanol from a gaseous mixture

I have a gaseous mixture (air) at a temperature of approximately 30 degrees Celsius in which the following gases are present: Oxygen 0 - 25% Carbon Dioxide 0 - 20% Methanol 0 - 100 ppm? Ethanol 0 - ...
DenmarkViking's user avatar
0 votes
1 answer
308 views

What is ionic reaction equation for reaction between carbon dioxide and limewater?

Write the ionic reaction equation for the reaction \[\ce{Ca(OH)2(aq) + CO2(g) <=> CaCO3(s) + H2O(l)}.\] I first wrote the complete ionic equation as such: \[\ce{Ca^2+ + 2 OH^- + CO2 <=> ...
youthdoo's user avatar
  • 133
1 vote
1 answer
105 views

What is the maximum number of silver(Ⅰ) ions in one litre of a 0.003 M sodium sulfide solution?

What is the maximum number of silver(Ⅰ) ions that can be present dissolved in one litre of a $\pu{0.003 M}$ $\ce{Na2S}$ solution? According to my book, silver(I) reacts with sulfide producing $\ce{...
wengen's user avatar
  • 423
-3 votes
2 answers
821 views

Are solubility product (Ksp) and dissociation constant (Kd) unrelated? [closed]

Dissociation constant can be calculated from the Gibb's energy released by the dissociation, but as best I can tell, there's no way to determine solubility from dissociation constant, as things can ...
Liam Clink's user avatar
2 votes
2 answers
147 views

Find the added volume of HCl so that the ions separate

Suppose we have a 10mL solution that contains 0.02M $\ce{Ag^+}$ and 0.04M $\ce{Ba^{2+}}$. a) Find the necessary volume to be added of $\ce{HCl}$ to separate all the silver. (Assume to be separated if ...
Aley20's user avatar
  • 53
-1 votes
1 answer
257 views

Is lead iodide a strong electrolyte?

So, lead iodide is insoluble. I see conflicting answers online. Some say it's a weak electrolyte because it is insoluble, others say it is a strong electrolyte because it is an ionic compound and any ...
blazerunner's user avatar
9 votes
3 answers
3k views

Why is there a decrease in the total volume when NaOH dissolves in water?

When a solute is added to a solvent, the volume of the solution should be equal to the sum of the individual volume of the solute and solvent (i.e total volume), right? But why is there a decrease in ...
Yitian Chen's user avatar
2 votes
1 answer
243 views

Solubility comparison for para-nitrophenol and phenol

During lecture with our chemistry teacher, he randomly asked us to compare solubility of phenol and p-nitrophenol, we expected p-nitrophenol to have greater solubility than phenol due to better dipole ...
Vaasu Kansal's user avatar
0 votes
0 answers
51 views

How to measure pottery glaze leaching?

I am looking for a way to know if glazes from pottery leach chemical compound in water. Those are usually metal ions: cobalt, manganese, chrome, etc. The procedure would be to place hot water in the ...
alfor's user avatar
  • 1
-2 votes
2 answers
732 views

Isolating potassium chloride from sodium chloride and potassium hydroxide

Assume that you have an aqueous solution of sodium chloride and potassium hydroxide. Is it possible to isolate potassium chloride from this? $$\ce{Na+(aq) + Cl-(aq) + K+(aq) + OH-(aq) -> Na+(aq) + ...
user avatar
1 vote
1 answer
208 views

What is the effect of adding another solute to the solubility of the initial solute?

Let's say we have a saturated salt solution with 35 g/100 mL NaCl in water. If we add another solute up to its saturation concentration, for example 182 g/100 ml sucrose (C12H22O11), what happens? ...
user123456789's user avatar
0 votes
0 answers
65 views

Solubility of multiple solutes and limits of solubility during freezing

I'm interested in modeling the freezing of solutions of water and I'm not really sure what happens in water after the solubility of a given material is reached. I know that as ice crystals form they ...
Jake's user avatar
  • 217
-1 votes
1 answer
955 views

Solubility of nitrogen dioxide in sodium hydroxide

I know $\ce{NaOH}$ can absorb $\ce{NO2}$, but I could not find any data of solubility of $\ce{NO2}$ in $\ce{NaOH}$ at room temperature and atmospheric pressure. I am trying to figure out how much NaOH ...
user510's user avatar
  • 864
3 votes
0 answers
39 views

Maintaining our supersaturated oceans

Supersaturates solutions can be unstable and decay beautifully once a seed crystal is introduced. Our oceans near the surface are supersaturated with respect to calcium carbonate. This map shows the ...
Kevin Kostlan's user avatar
0 votes
0 answers
213 views

Which method has the highest yield of calcium sulfate?

I'm not sure which of following two methods will give better yields for $\ce{CaSO4}$: A. Add dilute $\ce{HNO3}$ to $\ce{CaCO3}$, followed by dilute $\ce{H2SO4}$; or B. Titrate aqeuous calcium ...
Ben Chua's user avatar
4 votes
1 answer
3k views

Why is Maleic Acid more soluble in water than its trans isomer Fumaric Acid?

My teacher taught me that compounds having intramolecular H-Bonding are relatively less soluble in water as they will not involve in H-Bonding with water appreciably while those able to do ...
Swapnil Kashyap's user avatar
0 votes
1 answer
1k views

How to make silicic acid, potassium silicate or calcium silicate?

I am a student of tropical agriculture. I am taking the class of agronomic chemistry and plant nutrition. I want to make use of silicate source I have at home for e.g. zeolite, wood ashes, ...
Jared Yair De La Torriente Gut's user avatar
-4 votes
2 answers
242 views

Milliliters of NaBr when changing molarity [closed]

I was very confused by this problem. I was able to get the molarity, but I wasn’t certain how to go from there: If $\pu{2.60 g}$ of $\ce{NaBr}$ is dissolved in enough water to make $\pu{160.0 mL}$ of ...
Alex's user avatar
  • 99
0 votes
0 answers
126 views

Why is the Ag+ concentration in a beaker fixed in the reaction between excess AgCl (s) and KI (aq) from the start? [duplicate]

This arises as a sub-question for the following question: Calculate the concentration of I- in a solution obtained by mixing 0.10 M KI with an excess of AgCl(s). I tried to look at How does addition ...
chemcurious's user avatar
0 votes
2 answers
1k views

How does addition of AgCl affect concentration of iodide in KI solution?

In a mixture of $\ce{AgCl(s)}$ and initial $\pu{0.10 M}$ $\ce{KI}$, what is the $[\ce{I-}]$ after the reaction proceeds? Disclaimer: This is not a graded assignment, but rather a problem I'm trying to ...
user105739's user avatar
1 vote
1 answer
463 views

MgO as food supplement - solubility in water

A number of magnesium food / sports supplements contain it as MgO - which is practically unsoluble in water. The recommended quantity is somewhere around .3g / day, so not an insignificant amount. How ...
Zubo's user avatar
  • 1,220
2 votes
2 answers
116 views

Criterion for gravimetric analysis of silver

If the only criterion for gravimetric analysis of silver is solubility of precipitate, which one of the following two compound are we supposed to choose? $K_\mathrm{s}(\ce{AgCl}) = \pu{1.78E-10}$ and ...
OthersAl's user avatar
2 votes
2 answers
2k views

Do strong acids actually dissociate completely?

Do strong acids actually dissociate completely (every single molecule dissociates), or are they just assumed to do so for the sake of simplicity? That seems odd, considering weak acids, many of which ...
The_CIA's user avatar
  • 119
0 votes
0 answers
138 views

Aluminum Monoacetate Solubility in Aqueous Medium?

Does anyone have access to the aqueous solubility value of aluminum monoacetate? I would expect it to be slightly soluble but I've searched the internet and haven't found any solubility values. : /
Hans's user avatar
  • 1,097
0 votes
1 answer
911 views

Water solubility of different types of Iron III

For an experiment I require an aqueous solution of Iron(III). My school has the following compounds, which of them are water soluble? I believe that only Iron(III) oxide is insoluble, but I would like ...
acertainfruit's user avatar
0 votes
0 answers
109 views

Comparative Solubility of Double Salts

Is there a tendency that could be used to generally forecast how a double salt might dissolve in aqueous medium compared to the simple salts of its constituents? Example: There is metal A, metal B and ...
Hans's user avatar
  • 1,097
0 votes
1 answer
213 views

Effect of mixing acids on solubility

Please help me clarify the title if you come up with a better way to put it (you certainly will). My question is the following: If you make a mix of equal parts of various acids (Bicarbonate, ...
Hans's user avatar
  • 1,097
-1 votes
1 answer
953 views

How does chromium behave in a carbonate solution? [closed]

I'm wondering how chromium (as a metal or as a salt) behaves in a concentrated carbonate solution. Will it form any, one or several carbonate specie(s)? Will the metal solubilize? How does it affect ...
Hans's user avatar
  • 1,097
0 votes
1 answer
68 views

NaHCO3 decomposition dynamics and extent vs Temperature

I'm wondering approximately how fast and to which extent $\ce{NaHCO3}$ will decompose (to $\ce{CO2}$ and $\ce{H2O}$) at $50$, $60$, $70$, $80$, $90$, $100$, $110$, $120$, and $\pu{130 ^\circ C}$. It ...
Hans's user avatar
  • 1,097
1 vote
1 answer
83 views

Are all gases equal in their ability to carry with them lower volatility matter at a given temperature? [closed]

As we all know water is a great solvent in it's liquid form relative to other substances. I wonder however how it performs as a gas relative to other stuff. Does anyone know how well steam carries ...
Hans's user avatar
  • 1,097
0 votes
2 answers
3k views

Is an aqueous solution of potassium bicarbonate acidic or basic in nature?

The following is the definition of an acid salt according to my textbook: The salts formed by the partial replacement of the replaceable hydrogen atoms (H+ ions) of an acid molecule by a metallic or ...
Curious 's user avatar
0 votes
1 answer
259 views

Creating 100mg/L aspirin solution

I plan on creating 100 mL of 100mg/L aspirin solution by dissolving 10 mg of pure aspirin powder in 100 mL of buffer solution (of different pHs). Problematically, aspirin doesn’t tend towards ...
Mas's user avatar
  • 467
2 votes
2 answers
289 views

Does K2CO3 react in minute amounts with glassware at higher temperatures?

At a temperature of $\pu{750 ^\circ C}$, $\ce{K2CO3}$ and $\ce{SiO2}$ react with each other in substantial proportions, forming $\ce{K2SiO3}$ and $\ce{CO2}$ in the process$\ce{^{[1]}}$. We all know as ...
Hans's user avatar
  • 1,097
3 votes
0 answers
497 views

The most convenient process to purify Oxalic Acid up to a high level of purity

I am set out to purify a batch of commercial oxalic acid with the aim in mind to end up with a highly pure product (starting from $\pu{4,000 ppm}$ total impurities and doing so with basic lab ...
Hans's user avatar
  • 1,097
9 votes
1 answer
699 views

Why is the water solubility of CO worse than that of CO2?

I tried my best to ask SciFinder, Google, and Google Scholar the wrong questions ... I found many paper on the fitting of the solubility to some equations to be able to calculate the amount of $\ce{CO}...
pH13 - Yet another Philipp's user avatar
1 vote
1 answer
2k views

Using solubility product to determine the mass of the precipitate of a reaction

I mix together $\pu{100 mL}$ of an aqueous $\ce{NaCl}$ solution at $\pu{0.5 M}$ and $\pu{100 mL}$ of an aqueous $\ce{AgNO3}$ solution at $\pu{0.3 M}$. Assuming that the solubility of $\ce{NaCl}$ in ...
agg199's user avatar
  • 11
0 votes
2 answers
712 views

How to calculate mass of calcium fluoride that will dissolve in sodium fluoride solution?

The solubility product of calcium fluoride, $\ce{CaF2},$ is $\pu{1.46E-10 mol^3 dm^{-9}.}$ What mass of calcium fluoride will dissolve in $\pu{500 cm^3}$ of $\pu{0.10 mol dm^{-3}}$ sodium fluoride ...
gc3941d's user avatar
  • 145
0 votes
1 answer
1k views

Why is the solubility of calcium sulfate so low even though it is a salt? [duplicate]

What is the reason the solubility of calcium sulfate in water is so low? Compared to other salts like potassium sulfate (110 g/L) or calcium nitrate (1470 g/L) the solubility of calcium sulfate seems ...
CuriousIndeed's user avatar
1 vote
0 answers
266 views

Two salts in mutual saturation, which one will precipitate first? [closed]

Let's say I have a satuated solution of two salts with a common ion e.g. KCl and KI, and they're at mutual saturation (let's say there are 75% by weight KCl/ 25% KI). If I slowly evaporate some water, ...
R. Wang's user avatar
  • 219
1 vote
1 answer
77 views

Seeing solubility in various cases

Match the following: $\begin{array}{|c|c|c|c|} \hline &\textrm{Column-I}&&\textrm{Column-II} \\\hline \textrm{(A)}&\ce{AgBr}&\mathrm{(p)}&\mathrm{(Solubility~in~water~is~more~...
SM Sheikh's user avatar
  • 111
0 votes
1 answer
75 views

Does PEO particle size decrease when dissolved in water?

I am looking to make metallic ink for inkjet printing and using PEO 1 wt% (MW ~600,000) as a binder. The print head I am hoping to use has a nozzle diameter of 80 microns. The metal powder dispersed ...
JoC5's user avatar
  • 11

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