All Questions
Tagged with aqueous-solution solubility
209
questions
2
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1
answer
67
views
Does solubility product dictate predominant precipitate from the solution with several ionic compounds?
While removing temporary hardness through boiling, magnesium bicarbonate will give $\ce{Mg(OH)2}.$ $\ce{Mg(OH)2}$ predominates over $\ce{MgCO3}$ as the solubility product $K_\mathrm{sp}$ of $\ce{Mg(OH)...
1
vote
0
answers
375
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Who is more polar: acetonitrile or methanol?
According to data dipole moment of acetonitrile is around 4 while that of methanol is 1.7 but is said that acetonitrile is more soluble in non polar solvent that methanol.
But shouldn't methanol be ...
2
votes
2
answers
145
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In an unsaturated solution, is the product of ions still equal to Ksp?
Suppose I have a solution of a sparingly soluble compound, and consider its solubility in g/L. If I have less g/L of solution than that amount, it means the solution is unsaturated, but what happens ...
-1
votes
1
answer
44
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Solubility of hydrogen
I'm interested in bacterial fermentation which produces molecular hydrogen as an end product. If bacteria produce molecular hydrogen in solution under anaerobic conditions, does this remain dissolved ...
1
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0
answers
75
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What does it mean for a substance to be "sparingly soluble"?
I have trouble understanding what solubility means. Merriam-Webster defines it as follows:
1 the quality or state of being soluble
2 the amount of a substance that will dissolve in a given amount of ...
-2
votes
1
answer
118
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Small (personal) scale sea salt production?
I was looking to try to make a small setup for producing small amounts of sea salt. Ideally a series of evaporation chambers, with a heavy brine as the finished product, that could then be baked. May ...
1
vote
1
answer
157
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Solubility of SrF2 in aqueous solution of NaF
This might be really simple question but I have no idea how to proceed to solve such kind of question.
The solubility product of $\ce{SrF2}$ in water is $\pu{8E-10}$. Calculate its solubility in 0.1M ...
2
votes
1
answer
103
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Equilibrium Solubility of CO2 in Aqueous Solution and its Dependence on H3O+ Concentration
The equilibrium solubility of $\ce{CO2}$ in an aqueous solution is given by three chemical reactions:
$$
\begin{align}
\ce{CO2(g) &<=> CO2(aq)}\label{rxn:R1}\tag{R1}\\
\ce{CO2(aq) + H2O &...
2
votes
1
answer
86
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Are all salts completely dissociated in solution when put in smaller amounts than their molar solubility?
From what I understand, the solubility is given in terms of molar solubility (or $\pu{K_{sp}}$), from which it can be easily calculated). Indeed, the saturation point represents the maximum amount of ...
1
vote
1
answer
117
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Scrubbing methanol and ethanol from a gaseous mixture
I have a gaseous mixture (air) at a temperature of approximately 30 degrees Celsius in which the following gases are present:
Oxygen 0 - 25%
Carbon Dioxide 0 - 20%
Methanol 0 - 100 ppm?
Ethanol 0 - ...
0
votes
1
answer
308
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What is ionic reaction equation for reaction between carbon dioxide and limewater?
Write the ionic reaction equation for the reaction
\[\ce{Ca(OH)2(aq) + CO2(g) <=> CaCO3(s) + H2O(l)}.\]
I first wrote the complete ionic equation as such:
\[\ce{Ca^2+ + 2 OH^- + CO2 <=> ...
1
vote
1
answer
105
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What is the maximum number of silver(Ⅰ) ions in one litre of a 0.003 M sodium sulfide solution?
What is the maximum number of silver(Ⅰ) ions that can be present dissolved in one litre of a $\pu{0.003 M}$ $\ce{Na2S}$ solution?
According to my book, silver(I) reacts with sulfide producing $\ce{...
-3
votes
2
answers
821
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Are solubility product (Ksp) and dissociation constant (Kd) unrelated? [closed]
Dissociation constant can be calculated from the Gibb's energy released by the dissociation, but as best I can tell, there's no way to determine solubility from dissociation constant, as things can ...
2
votes
2
answers
147
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Find the added volume of HCl so that the ions separate
Suppose we have a 10mL solution that contains 0.02M $\ce{Ag^+}$ and 0.04M $\ce{Ba^{2+}}$. a) Find the necessary volume to be added of $\ce{HCl}$ to separate all the silver. (Assume to be separated if ...
-1
votes
1
answer
257
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Is lead iodide a strong electrolyte?
So, lead iodide is insoluble. I see conflicting answers online. Some say it's a weak electrolyte because it is insoluble, others say it is a strong electrolyte because it is an ionic compound and any ...
9
votes
3
answers
3k
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Why is there a decrease in the total volume when NaOH dissolves in water?
When a solute is added to a solvent, the volume of the solution should be equal to the sum of the individual volume of the solute and solvent (i.e total volume), right? But why is there a decrease in ...
2
votes
1
answer
243
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Solubility comparison for para-nitrophenol and phenol
During lecture with our chemistry teacher, he randomly asked us to compare solubility of phenol and p-nitrophenol, we expected p-nitrophenol to have greater solubility than phenol due to better dipole ...
0
votes
0
answers
51
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How to measure pottery glaze leaching?
I am looking for a way to know if glazes from pottery leach chemical compound in water.
Those are usually metal ions: cobalt, manganese, chrome, etc.
The procedure would be to place hot water in the ...
-2
votes
2
answers
732
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Isolating potassium chloride from sodium chloride and potassium hydroxide
Assume that you have an aqueous solution of sodium chloride and potassium hydroxide. Is it possible to isolate potassium chloride from this?
$$\ce{Na+(aq) + Cl-(aq) + K+(aq) + OH-(aq) -> Na+(aq) + ...
1
vote
1
answer
208
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What is the effect of adding another solute to the solubility of the initial solute?
Let's say we have a saturated salt solution with 35 g/100 mL NaCl in water. If we add another solute up to its saturation concentration, for example 182 g/100 ml sucrose (C12H22O11), what happens?
...
0
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0
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65
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Solubility of multiple solutes and limits of solubility during freezing
I'm interested in modeling the freezing of solutions of water and I'm not really sure what happens in water after the solubility of a given material is reached. I know that as ice crystals form they ...
-1
votes
1
answer
955
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Solubility of nitrogen dioxide in sodium hydroxide
I know $\ce{NaOH}$ can absorb $\ce{NO2}$, but I could not find any data of solubility of $\ce{NO2}$ in $\ce{NaOH}$ at room temperature and atmospheric pressure.
I am trying to figure out how much NaOH ...
3
votes
0
answers
39
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Maintaining our supersaturated oceans
Supersaturates solutions can be unstable and decay beautifully once a seed crystal is introduced.
Our oceans near the surface are supersaturated with respect to calcium carbonate. This map shows the ...
0
votes
0
answers
213
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Which method has the highest yield of calcium sulfate?
I'm not sure which of following two methods will give better yields for $\ce{CaSO4}$:
A. Add dilute $\ce{HNO3}$ to $\ce{CaCO3}$, followed by dilute $\ce{H2SO4}$; or
B. Titrate aqeuous calcium ...
4
votes
1
answer
3k
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Why is Maleic Acid more soluble in water than its trans isomer Fumaric Acid?
My teacher taught me that compounds having intramolecular H-Bonding are relatively less soluble in water as they will not involve in H-Bonding with water appreciably while those able to do ...
0
votes
1
answer
1k
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How to make silicic acid, potassium silicate or calcium silicate?
I am a student of tropical agriculture. I am taking the class of agronomic chemistry and plant nutrition. I want to make use of silicate source I have at home for e.g. zeolite, wood ashes, ...
-4
votes
2
answers
242
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Milliliters of NaBr when changing molarity [closed]
I was very confused by this problem. I was able to get the molarity, but I wasn’t certain how to go from there:
If $\pu{2.60 g}$ of $\ce{NaBr}$ is dissolved in enough water to make $\pu{160.0 mL}$ of ...
0
votes
0
answers
126
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Why is the Ag+ concentration in a beaker fixed in the reaction between excess AgCl (s) and KI (aq) from the start? [duplicate]
This arises as a sub-question for the following question: Calculate the concentration of I- in a solution obtained by mixing 0.10 M KI with an excess of AgCl(s).
I tried to look at How does addition ...
0
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2
answers
1k
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How does addition of AgCl affect concentration of iodide in KI solution?
In a mixture of $\ce{AgCl(s)}$ and initial $\pu{0.10 M}$ $\ce{KI}$, what is the $[\ce{I-}]$ after the reaction proceeds?
Disclaimer: This is not a graded assignment, but rather a problem I'm trying to ...
1
vote
1
answer
463
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MgO as food supplement - solubility in water
A number of magnesium food / sports supplements contain it as MgO - which is practically unsoluble in water. The recommended quantity is somewhere around .3g / day, so not an insignificant amount.
How ...
2
votes
2
answers
116
views
Criterion for gravimetric analysis of silver
If the only criterion for gravimetric analysis of silver is solubility of precipitate, which one of the following two compound are we supposed to choose? $K_\mathrm{s}(\ce{AgCl}) = \pu{1.78E-10}$ and ...
2
votes
2
answers
2k
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Do strong acids actually dissociate completely?
Do strong acids actually dissociate completely (every single molecule dissociates), or are they just assumed to do so for the sake of simplicity? That seems odd, considering weak acids, many of which ...
0
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0
answers
138
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Aluminum Monoacetate Solubility in Aqueous Medium?
Does anyone have access to the aqueous solubility value of aluminum monoacetate?
I would expect it to be slightly soluble but I've searched the internet and haven't found any solubility values. : /
0
votes
1
answer
911
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Water solubility of different types of Iron III
For an experiment I require an aqueous solution of Iron(III). My school has the following compounds, which of them are water soluble? I believe that only Iron(III) oxide is insoluble, but I would like ...
0
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0
answers
109
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Comparative Solubility of Double Salts
Is there a tendency that could be used to generally forecast how a double salt might dissolve in aqueous medium compared to the simple salts of its constituents?
Example:
There is metal A, metal B and ...
0
votes
1
answer
213
views
Effect of mixing acids on solubility
Please help me clarify the title if you come up with a better way to put it (you certainly will).
My question is the following:
If you make a mix of equal parts of various acids (Bicarbonate, ...
-1
votes
1
answer
953
views
How does chromium behave in a carbonate solution? [closed]
I'm wondering how chromium (as a metal or as a salt) behaves in a concentrated carbonate solution. Will it form any, one or several carbonate specie(s)? Will the metal solubilize? How does it affect ...
0
votes
1
answer
68
views
NaHCO3 decomposition dynamics and extent vs Temperature
I'm wondering approximately how fast and to which extent $\ce{NaHCO3}$ will decompose (to $\ce{CO2}$ and $\ce{H2O}$) at $50$, $60$, $70$, $80$, $90$, $100$, $110$, $120$, and $\pu{130 ^\circ C}$.
It ...
1
vote
1
answer
83
views
Are all gases equal in their ability to carry with them lower volatility matter at a given temperature? [closed]
As we all know water is a great solvent in it's liquid form relative to other substances. I wonder however how it performs as a gas relative to other stuff.
Does anyone know how well steam carries ...
0
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2
answers
3k
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Is an aqueous solution of potassium bicarbonate acidic or basic in nature?
The following is the definition of an acid salt according to my textbook:
The salts formed by the partial replacement of the replaceable hydrogen atoms (H+ ions) of an acid molecule by a metallic or ...
0
votes
1
answer
259
views
Creating 100mg/L aspirin solution
I plan on creating 100 mL of 100mg/L aspirin solution by dissolving 10 mg of pure aspirin powder in 100 mL of buffer solution (of different pHs). Problematically, aspirin doesn’t tend towards ...
2
votes
2
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289
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Does K2CO3 react in minute amounts with glassware at higher temperatures?
At a temperature of $\pu{750 ^\circ C}$, $\ce{K2CO3}$ and $\ce{SiO2}$ react with each other in substantial proportions, forming $\ce{K2SiO3}$ and $\ce{CO2}$ in the process$\ce{^{[1]}}$.
We all know as ...
3
votes
0
answers
497
views
The most convenient process to purify Oxalic Acid up to a high level of purity
I am set out to purify a batch of commercial oxalic acid with the aim in mind to end up with a highly pure product (starting from $\pu{4,000 ppm}$ total impurities and doing so with basic lab ...
9
votes
1
answer
699
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Why is the water solubility of CO worse than that of CO2?
I tried my best to ask SciFinder, Google, and Google Scholar the wrong questions ...
I found many paper on the fitting of the solubility to some equations to be able to calculate the amount of $\ce{CO}...
1
vote
1
answer
2k
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Using solubility product to determine the mass of the precipitate of a reaction
I mix together $\pu{100 mL}$ of an aqueous $\ce{NaCl}$ solution at $\pu{0.5 M}$ and $\pu{100 mL}$ of an aqueous $\ce{AgNO3}$ solution at $\pu{0.3 M}$. Assuming that the solubility of $\ce{NaCl}$ in ...
0
votes
2
answers
712
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How to calculate mass of calcium fluoride that will dissolve in sodium fluoride solution?
The solubility product of calcium fluoride, $\ce{CaF2},$ is $\pu{1.46E-10 mol^3 dm^{-9}.}$
What mass of calcium fluoride will dissolve in $\pu{500 cm^3}$ of $\pu{0.10 mol dm^{-3}}$ sodium fluoride ...
0
votes
1
answer
1k
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Why is the solubility of calcium sulfate so low even though it is a salt? [duplicate]
What is the reason the solubility of calcium sulfate in water is so low? Compared to other salts like potassium sulfate (110 g/L) or calcium nitrate (1470 g/L) the solubility of calcium sulfate seems ...
1
vote
0
answers
266
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Two salts in mutual saturation, which one will precipitate first? [closed]
Let's say I have a satuated solution of two salts with a common ion e.g. KCl and KI, and they're at mutual saturation (let's say there are 75% by weight KCl/ 25% KI). If I slowly evaporate some water, ...
1
vote
1
answer
77
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Seeing solubility in various cases
Match the following:
$\begin{array}{|c|c|c|c|} \hline &\textrm{Column-I}&&\textrm{Column-II} \\\hline \textrm{(A)}&\ce{AgBr}&\mathrm{(p)}&\mathrm{(Solubility~in~water~is~more~...
0
votes
1
answer
75
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Does PEO particle size decrease when dissolved in water?
I am looking to make metallic ink for inkjet printing and using PEO 1 wt% (MW ~600,000) as a binder. The print head I am hoping to use has a nozzle diameter of 80 microns. The metal powder dispersed ...