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28 votes
7 answers
22k views

Why is silver chloride less soluble than silver nitrate?

Related: Reaction between silver nitrate and aluminum chloride Experimentally, $\ce{AgCl}$ is insoluble in water, but $\ce{AgNO3}$ is soluble. They're pretty common in a lab (well, $\ce{AgCl}$ is a ...
ManishEarth's user avatar
  • 15.2k
20 votes
2 answers
1k views

Hydration of H⁺ ion

I know that $\ce{H+}$ is not possible in water and it is present as $\ce{H3O+}$. But later on I come to know that even $\ce{H3O+}$ is not possible and that it is present as $\ce{H9O4+}$. Why does this ...
Ashu's user avatar
  • 1,453
13 votes
2 answers
8k views

Why does the ionic product of water remain constant after addition of non-neutral solute?

In my textbook, it is given that the ionic product of water $K_\mathrm{w}$ remains constant even when a non-neutral solute such as an acid is added to it. $$K_\mathrm{w} = \ce{[H3O+][OH-]}$$ When a ...
Gaurav's user avatar
  • 295
12 votes
3 answers
38k views

Differentiation between zinc, aluminium, and magnesium ions in solution

If I have three aqueous ionic solutions in which I know that the cation is $\ce{Al^3+}$, $\ce{Mg^2+}$, or $\ce{Zn^2+}$, how do I find out which is which? I was thinking to add $\ce{OH-}$ in the form ...
dma1324's user avatar
  • 223
10 votes
1 answer
10k views

How does the HCl-KCl Buffer work?

I have just been studying the $\ce{HCl}$-$\ce{KCl}$ 'buffer', but there are still quite a few things I am uncertain about. I would appreciate any help in clearing up some questions I have. What I ...
leob's user avatar
  • 445
7 votes
1 answer
1k views

Is there a material that ions can pass through but water can’t?

I was wondering whether there is a material that can pass ions (such as the ions existing in seawater) but not water. I am aware that water molecules are smaller, so they can pass through some ...
Belal Bahaa's user avatar
7 votes
1 answer
7k views

Does iron(III) sulfate react with copper?

As my understanding, there should be an oxidation-reduction reaction: $$ \ce{2 Fe^3+ + Cu → 2Fe^2+ + Cu^2+} $$ However, I always see the process using $\ce{FeCl3}$ to etch copper, but I never ...
Carl Dong's user avatar
  • 173
6 votes
1 answer
5k views

Hybridization of Na in [Na(H2O)6]+

In the complex ion $\ce{[Na(H2O)6]+}$, the sodium cation forms 6 coordinate bonds with water ligands. Typically this octahedral form is associated with $\mathrm{sp^3d^2}$ hybridization as far as I ...
Goods's user avatar
  • 723
6 votes
1 answer
50k views

Net ionic equation with only aqueous ions

When you turn a balanced equation into a net ionic equation, you ignore all the ions that are spectator ions (aqueous on one side as well as the other). You only write the solid and the aqueous ions ...
pjrader1's user avatar
  • 181
6 votes
1 answer
4k views

What is the exact definition of Salinity?

I am a bit unclear on the definition of salinity. I have always thought of it as simply total dissolved ions. Wikipedia seems to agree "saltiness or dissolved salt content" but many other sources ...
Cargo's user avatar
  • 792
5 votes
2 answers
3k views

Calculating approximate pH of polyprotic acids

When I took up ionic equilibria and titrations after a long break, I found it hard to solve the questions regarding pH calculations of polyprotic acds. Consider these two questions as examples:- ...
stochastic13's user avatar
  • 6,795
5 votes
1 answer
3k views

What happens to potassium if potassium permanganate is reduced in a redox reaction? How can I identify spectator ions?

I'm trying to get a fool-proof way of finding the products of a redox reaction. I can do both the oxidation and reduction the half reactions. For example in the potassium permanganate with hydrogen ...
Padraig Stapleton's user avatar
5 votes
1 answer
2k views

How is tea affecting water's color?

Black tea is an amazing product of the green tea leaves. A recent study has proven that; The anion profile for the tea solution indicated that oxalate and citrate were the major anions detected. ...
M.A.R.'s user avatar
  • 10.7k
5 votes
1 answer
749 views

Trichloride ion (c.f. triiodide ion)

While triiodide ion is commonly known, why is that trichloride ion (and its salts) almost unheard of? While it does exist according to literature, why is the stability of trichloride ion in aqueous ...
Sunny's user avatar
  • 51
4 votes
2 answers
20k views

CuCl2 dissolved in water

We dissolve $10\ \mathrm{g}$ of $\ce{CuCl2}$ in $0.1\ \mathrm{L}$ of water. Given that: $M(\ce{Cl})=35.5\ \mathrm{g/mol}$ $M(\ce{Cu})=63.5\ \mathrm{g/mol}$ How can one calculate the molar ...
user233658's user avatar

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