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7 votes
3 answers
2k views

In my homemade electrolysis setup, only the negative end bubbles?

I've created an electrolysis setup by connecting a $6~\mathrm{V}$ battery to a cup filled with saline water via pencils; I am confused as to why only the negative pencil bubbles though. After running ...
Rob Dawson's user avatar
6 votes
2 answers
31k views

Electrolysis of aqueous copper (II) nitrate

There are two copper blocks sitting in the $\ce{Cu(NO3)2 (aq)}$ solution, a battery is attached onto both of them, providing enough energy to start the reaction. Since solid pieces of copper are ...
Dave Chen's user avatar
  • 257
5 votes
1 answer
636 views

Electrolysis of water for demonstration: ideal electrolyte for safety, stability, conductivity, and ease of maintenance

I'm developing a system for educational purposes where electrolysis of water takes place. The aim is to practically show how electrical energy can be converted to mechanical, by electrolyzing water, ...
oxullo's user avatar
  • 153
5 votes
1 answer
235 views

Change of potential difference during electrolysis while adding salt

I was conducting a simple experiment at home on electrolysis. Obviously, when you build a circuit with a 9V battery, a lamp, and put two electrodes in water you measure a potential difference of ~9V ...
flavio salvati's user avatar
4 votes
1 answer
3k views

How does KMnO₄ affect electrolysis?

I'm just blindly experimenting. I tried to dissolve some potassium permanganate in water before performing electrolysis. I can't see much difference. How is $\ce{KMnO4}$ dissolved in water? How does ...
Tomáš Zato's user avatar
  • 2,518
4 votes
1 answer
224 views

Do ion-exchange membranes *always* require ions to pass in both directions?

In an answer to this question, it was asserted that: Student always tend to forget that a solution must remain electrically neutral by all means. If you want a certain ion to leave water, you must ...
abligh's user avatar
  • 189
4 votes
1 answer
95 views

Why is my Ni or Fe cathode blackening and pores getting blocked during alkaline (6 M KOH) electrolysis?

I am conducting an electrolysis process for hydrogen $(\ce{H2})$ and oxygen $(\ce{O2})$ generation using a $\pu{6 M}$ $\ce{KOH}$ alkaline solution. During the process, I have observed that my cathode ...
Bhavik Modi's user avatar
3 votes
3 answers
3k views

How to separate a mixture of sodium chloride and sodium hydroxide?

I recently did a double displacement reaction in which I formed a solution of water with sodium hydroxide and sodium chloride dissolved in it. Now I want to separate both of them. How can I do this?
zuha's user avatar
  • 39
3 votes
1 answer
55 views

Experiment on pH vs Rate of Electrolysis - what do the results actually say?

My experimental setup looks at using different pH solutions (of $\ce{H2SO4}$ and $\ce{NaOH}$) for electrolysis of water with a Hoffman setup and then measuring the rate of production of gas (note this ...
Eshwar Kolli's user avatar
3 votes
0 answers
80 views

Can a brine water electrolysis be looped?

Electrolysis of brine yields hydrogen and chlorine gases and aqueous $\ce{NaOH}$. So is it possible to combine the gases to form $\ce{HCl}$ gas, and mix it back with the aqueous $\ce{NaOH}$, so it ...
Teki Haken's user avatar
3 votes
2 answers
25k views

Electrolysis of diluted sulfuric acid

My teacher told me that electrolysis of dil. $\ce{H2SO4}$ (concentration below $50\%$) using inert electrodes results in gradual increase of the concentration of $\ce{H2SO4}$. I can't seem to figure ...
Senthil Arihant's user avatar
2 votes
1 answer
3k views

Does electrolysis of aqueous tin(II) chloride produce Cl₂, SnCl₄ or both?

When applying a current to an aqueous solution of tin(II) chloride, tin crystals grow from the cathode. However, I'm not sure about the anode. It seems like there are two possible reactions: $$\ce{2 ...
Cheezey's user avatar
  • 123
2 votes
1 answer
1k views

Why isn't mercury electrode used to produce commercial element sodium?

I know that while electrolysing a solution of brine, if we use mercury cathode, we get sodium amalgam instead of having hydrogen gas liberated. Even the Castner-Kellner process uses this to produce ...
Pritt says Reinstate Monica's user avatar
2 votes
1 answer
10k views

Reaction of sulfate ion in copper sulfate electrolysis

I am planning to try copper plating a piece of metal by performing electrolysis on an aqueous solution of copper sulfate. I plan run an electrical current with the metal I want to plate as the cathode ...
Markovian8261's user avatar
2 votes
1 answer
46 views

Would ionic conduction be halted by shielding at the electrodes?

I've done this experiment myself and seen it front of my eyes. Set up a basic circuit with a battery, an LED, and connect the circuit with a salt-water solution and copper wire. The LED lights up. If ...
cheekylittleduck's user avatar

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