Randel Monroe's Mole of Moles essay does not apply here
The Mole of Moles essay assumes that all of the biomass is added at once in the absence of outside forces, meaning the stuff in the middle will not be able to decompose, but this planet is formed through accretion over time which yields a very different outcome.
Depending on how close you are too the star, this biomatter will either be frozen or cooked by the star's radiation before accreting. Since your civilization was aiming for the star, I will assume that you looking at very close orbit like mercury allowing most of the biomass to be very thoroughly cooked before it accretes. Cooking the biomass means that most of the gaseous elements (Like Hydrogen, Oxygen, and Nitrogen) will be liberated from the biomass and pushed off into deep space by solar winds while the less easily vaporized elements like carbon, calcium, and phosphorous will remain behind. This will result in an orbiting cloud of ash BEFORE it can come together to form a planet.
Over time this ashy cloud will form into asteroids that will collide forming bigger and bigger asteroids yielding increasingly energetic impacts until you get something big enough to sweep the orbit forming a planet. Since the new planet's core is non-ferrous, it will not form a magnetic field to protect it from solar radiation; so, any last remnants of water vapor or other gasses released will be quickly blown away into space. It also lacks enough radioactive isotopes to maintain a molten core; so, the core will quickly cool down and harden making it volcanically inert.
This will basically leave you with a planet made up of about 85% carbon, 7% calcium 5% phosphorous, 1.5% sulfur, and 1.5% other stuff.
In the birthing stage of your planet, rapid powerful accretion impacts will cause crystallization and shattering to occur meaning that your planet will likely have a regolith surface similar to the moon, but instead of being made mostly of oxides and silicates, it will be made mostly of things like graphite, diamonds, calcium carbide, and calcium phosphate.
So, to answer your question about the viability of life, you are missing many helpful ingredients like an atmosphere, magnetosphere, water, etc. However, the planet will contain a high volume of industrially useful compounds not widely found on normal planets; so, you may find intelligent life showing up to mine the place...