Today, I've successfully set up a home VPN router with OpenWrt and OpenVPN.
Since my VPN provider only supports IPv4 connections, I don't want network traffic to leak out and I've disabled IPv6 by unchecking "Internet Protocol Version 6" in the network adapter options in the Windows control panel.
Annoyingly, every time I go to university/work, I need to re-enable IPv6, because certain services provided by IT administration need IPv6 connectivity to function properly.
For convenience's sake, is there a way to disable IPv6 connectivity in Windows, only if I connect to my VPN router?