They could have, but the odds are that such windows will be relatively rare features reserved for, for example, an observation deck, as opposed to for letting in sunlight to grow plants.
Since this question is about viability, let's start by considering the most economically viable space settlement.
Al Globus made a pretty good case that the most economically viable space settlement should be built in a low equatorial earth orbit because then it would be close to Earth and relatively well shielded from space radiation by Earth's magnetic field. Inside such a habitat, we will need to create a 24-hour day-night cycle. Windows in a rotating habitat located in low earth orbit are not going to do that.
An approach that might make more sense would be to place solar panels on the outside of the habitat and use them to power LEDs on the inside of the habitat. I do recall a presenter at a conference that I attended some time ago saying that you can deliver more useful light to plants with solar panels and LEDs than you can by placing them in direct sunlight - even after factoring in the energy conversion losses.
For people (who do appreciate windows) a possible alternative might be to install large displays that create the illusion of a large window. At the rate we are progressing with developing display technology, by the time we build a space station the view we experience from an artificial window might very well be better than glass.
Another alternative to real windows might be to use advanced augmented reality headsets that simply render windows with beautiful views in the wearer's field of vision.
Other requirements influence the hull design for a space station. Good strength-to-weigh is important if you want to spin the station to create artificial gravity. The hull should help protect its occupants from meteorites and space debris (see Whipple shielding). Finally, there may be a need to provide some additional radiation shielding beyond what the Earth's magnetic field provides naturally. These requirements are not particularly compatible with a desire to include large transparent windows.
Conclusion
The primary reasons for large windows are: a) to provide "light food" for plants, and b) so that humans can see outside. Both of these requirements can be satisfied in other, potentially better, ways. Other requirements include the need for impact resistance, radiation shielding, and high specific strength. When considering all of the requirements together, large windows made from a transparent material will be far from ideal from an architectural or engineering perspective. For the time being - at least until our technology becomes a lot more advanced - every design choice will need to be pretty optimal for a space habitat to be viable.