I would like to add to Erin Anne's points about the mission design.
It helps to have a guiding thermal strategy (which will depend upon satellite pointing requirements etc) for the "primary heat loss path".
This is because, typically, one wants limited uncertainty over operating temperatures and, just by random example, a 50% uncertainty in something meant to be a good conductor will give a much lower temperature uncertainty than a 50% uncertainty in something meant to be an insulator. One probably wouldn't want insulators (e.g. MLI) all round a satellite unless the heat dissipation is particularly low.
Once you have worked out what your heat loads are and how to get rid of heat its easier to think in terms of insulating areas that are off the main heat loss path. Consider the sketch below. The temperature at the node at the top is a balance of the two paths.
I suggest trying to see the thermal problem in big picture terms like this, even if you have begun modelling and have a thermal model with hundreds of detailed links.
It will help to see some simplified worked examples, i.e. if you can see the overall strategy at satellite level for other designs.