Riker was always against Q's presence on the Enterprise, and his presence had put the Enterprise crew in risk before, not to mention judging the entire human race, and so I think that Riker wanted Q off the ship almost as much as the Calamarain did.
The Calamarain wanted vengeance on Q, and so presumably they didn't care whether he survived or not.
We know that the reason that they wanted revenge is because Q caused them great suffering, and so they would want to do the same to him.
There are 3 possibilities here (that I can see) as to how the Calamarain wanted to exact their vengeance:
1: The first is that they knew that Q was now vulnerable, but they didn't know he was human, and so they figured that they could cause him suffering, without necessarily killing him.
2: The second reason I can see is that they knew Q was human, and they knew that humans can survive in space for a very limited time, and this time would be excruciating to Q, and this would be seen as a good form of revenge.
3: Finally, the Calamarain could know that now Q was human, he would try to help the crew of the Enterprise and leave in a shuttle, giving them a ready-built way to keep Q alive to interrogate, or torture him.
I hope this helps!